Chlorohydrosilane derivatives and their preparation method
AssigneeKorea Institute of Science and Technology
InventorsIl Nam Jung, Bok Ryul Yoo, Joon Soo Han, Weon-Cheol Lim
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AssigneeKorea Institute of Science and Technology
InventorsIl Nam Jung, Bok Ryul Yoo, Joon Soo Han, Weon-Cheol Lim
Estimating the term…
New chlorohydrosilane derivatives having the general formula (I) and preparation method thereof. The chlorohydrosilane derivatives (I) of the present invention which have both Si--Cl and Si--H bonds are prepared by partially reducing chlorosilane of the formula (II) which have at least two Si--Cl bonds with lithiumaluminum hydride. The chlorohydrosilane derivatives (I) of the present invention, which have both Si--H and Si--Cl bonds in a molecule can be advantageously used in preparing various compounds because a Si--H bond enables the hydrosilylation with unsaturated organic compounds, while a Si--Cl bond can participate in hydrolysis or in a reaction with a nucleophilic compound such as Grignard reatent: ##STR1## wherein R.sup.1 is straight, branched, or cyclic alkyl group having 1 to 30 carbon atoms, which can include an aromatic group or heterocyclic group, and R.sup.2 represents chloro group, or straight, branched, or cyclic alkyl group having 1 to 30 carbon atoms, which can include an aromatic group or heterocyclic group.
A chlorohydrosilane derivatives having a general formula (I) as follows:
A method of preparing chlorohydrosilane having a general formula (I) comprising the reaction of chlorosilane of the formula (II) with lithiumaluminum hydride so that chlorosilane of the formula (II) is partially reduced to chlorohydrosilane of the formula (I):
Dependencies are inferred from the claim text.