Fibers made from long chain branched syndiotactic vinyl aromatic polymers
AssigneeThe Dow Chemical Company
InventorsCurtis E. Peterson, Yi-Bin Huang, Roel H. Vossen, Paul J. Moses, Jr.
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Abstract
Fibers having increased strength and small diameters can be produced from compositions comprising long chain branched syndiotactic vinyl aromatic polymers derived from the polymerization of a vinyl aromatic monomer in the presence of from 10 to 1000 ppm, based on the amount of vinyl aromatic monomer, of a multifunctional monomer having more than one olefinic functionality. Due to the increased fiber strength, less strand breakage occurs during processing which increases process productivity and yield.
Claims4
Fibers made from a composition comprising a long chain branched syndiotactic vinyl aromatic polymer derived from the polymerization of a vinyl aromatic monomer in the presence of from 10 to 1000 ppm, based on the amount of vinyl aromatic monomer, of a multifunctional monomer having more than one olefinic functionality as represented by the formula ##STR2## wherein R is a vinyl group or a group containing from 2 to 20 carbon atoms including a terminal vinyl group, wherein the groups containing 2 to 20 carbon atoms may be alkyl, alkenyl, cycloalkyl, or aromatic, wherein cycloalkyl groups contain at least 5 carbon atoms and aromatic groups contain at least 6 carbon atoms, n is an integer from 1 to 3 wherein the R groups are meta or para in relation to the vinyl group of formula (I), and when n is greater than 1, R may be the same or different.
Dependencies are inferred from the claim text.