Process for the preparation of supported metallocene catalyst
AssigneeCouncil of Scientific and Industrial Research
InventorsSwaminathan Sivaram, Soumen Sensarma
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AssigneeCouncil of Scientific and Industrial Research
InventorsSwaminathan Sivaram, Soumen Sensarma
Estimating the term…
This invention is directed to a process for the preparation of a supported metallocene catalyst, said process comprising preparing a precursor catalyst material by dissolving a magnesium halide in an electron donor solvent in which the magnesium halide is completely soluble, heating the solution to a temperature in the range of 20.degree. C. to the boiling point of the respective electron donor for a period ranging between 10 to 60 minutes, separately preparing a solution of the metallocene compound into the same electron donor solvent, heating the solution to a temperature in the range of 25.degree. C. to 70.degree. C. for a period ranging between 0.1 to 0.5 hrs., mixing the two solutions to obtain a homogenous solution of catalyst precursor compound, stirring and maintaining this resulting homogenous solution at a temperature in the range of 50.degree. C. to 70.degree. C. for a period of 0.5 to 2 hrs., separately preparing a slurry of support in a liquid hydrocarbon medium, heating the slurry to a temperature in the range of 50.degree. C. to 70.degree. C. and stirring it for a period of 0.25 to 2 hrs., mixing the homogenous solution of the catalyst precursor compound with the slurry of the support, stirring the resulting slurry for 0.5 to 3 hrs. maintaining at a temperature ranging between 50.degree. C to 70.degree. C., cooling the resultant slurry to room temperature under an inert atmosphere, separating the solid by conventional methods, washing the solid with a hydrocarbon solvent and drying the solid under vacuum to obtain the product.
A process for the preparation of a supported metallocene catalyst, which comprises preparing a precursor catalyst material, by preparing a solution (A) of a magnesium halide in an electron donor solvent in which the magnesium halide is completely soluble;
Dependencies are inferred from the claim text.