US 5,965,010 AGranted

Electrochemical autothermal reformer

AssigneeNiagara Mohawk Power Corporation

InventorsDavid P. Bloomfield, Arthur N. Rabe

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Abstract

An electrochemical autothermal reformer (EATR) provides hydrogen. The EATR includes an autothermal reformer region, a reformer anode supply region, and a composite membrane layer separating the reformer anode from the autothermal reformer region. The composite membrane layer includes a mechanically stable porous ceramic support member with a thin gas permeable ceramic substrate layer overlaying the support member. Overlaying the substrate layer is a first thin metallic catalyst layer which promotes the dissociation of H.sub.2 to 2H.sup.+ +2e.sup.-. Overlaying the first catalyst layer is a metallic oxide layer capable of conducting 2H.sup.+ +2e.sup.- at elevated temperatures. Overlaying the metallic oxide layer is a second thin metallic catalyst layer which promotes the recombination of 2H.sup.+ +2e.sup.- to H.sub.2.

Claims5

Dependent claims

A hydrogen forming and extraction process consisting of:

conducting in a hydrogen production zone a chemical reaction forming mixed gases comprising molecular hydrogen and other reaction products;
contacting one side of a composite membrane layer, which includes WO.sub.3 as a mixed ion layer sandwiched between two catalyst layers of particulate platinum, with said mixed gases in said hydrogen production zone;
with one of said catalyst layers functioning to promote the dissociation of H.sub.2 to protons and electrons and the second said catalyst layer functioning to promote the recombination of 2H.sup.+ +2e.sup.- .fwdarw.H.sub.2 ;
dissociating said molecular hydrogen to ionic or protonic hydrogen and associated electrons on said one side of said membrane layer, passing said ionic hydrogen through said membrane layer to another side of said membrane layer and recombining there with associated electrons to form molecular hydrogen;
and
withdrawing hydrogen from said another side of said membrane layer thereby removing hydrogen from said hydrogen production zone.

3 more elements

Dependencies are inferred from the claim text.