Alkylation of aromatics using a metal cation-modified friedel-crafts type catalyst

In the method for alkylating benzene with one or more linear monoolefins with at least 90% selectivity of olefin conversion to monoalkylbenzenes, and with at least 90% linearity with respect to monoalkylbenzene formation comprising reacting benzene with the linear monoolefins in a feedstock at alkylating conditions and in the presence of a catalyst, said feedstock containing at least one linear monoolefin, said alkylating conditions including reacting from about 5 to about 30 molar proportions of total benzene for each molar proportion of total linear monoolefins at a temperature from about 60.degree. C. to about 140.degree. C. and a pressure from about 200 to about 1000 psig, where the catalyst comprises a) a refractory inorganic oxide, b) the reaction product of a first metal halide and bound surface hydroxyl groups of said refractory inorganic oxide, c) a second metal cation, and d) optionally a zerovalent third metal;

• where said refractory inorganic oxide is selected from the group consisting of alumina, titania, zirconia, chromia, silica, boria, silica-alumina, and combinations thereof;
• said first metal halide is a fluoride, chloride, or bromide of aluminum;
• said second metal cation is selected from the group consisting of a) monovalent metal cations in an amount from 0.0026 up to about 0.20 gram atoms per 100 grams refractory inorganic oxide for lithium, potassium, cerium, rubidium, silver, and copper, and in an amount from 0.012 to about 0.12 gram atoms for sodium, and b) alkaline earth metal cations in an amount from about 0.0013 up to about 0.01 gram atoms per 100 grams of refractory inorganic oxide for beryllium, strontium, and barium, and an amount from about 0.004 up to about 0.1 gram atoms per 100 grams support for magnesium and calcium, and any combination thereof;
• and said third metal is selected from the group consisting of platinum, palladium, nickel, ruthenium, rhodium, osmium and iridium, and any combination thereof;
• the improvement comprising using a feedstock containing less than 0.1 ppm nitrogen, less than 0.2 ppm oxygenates, less than 0.1 ppm water, and less than 10 ppm sulfur.