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US 5,962,714 AGranted
Monocyclopentadienyl transition metal catalyst and olefin polymerization process
OwnerLaughlin Gerard McCullough, James C.W. Chien +2inventors
InventorsLaughlin Gerard McCullough, James C.W. Chien, Juan Carlos Flores, Marvin D. Rausch
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Abstract
Disclosed is a monocyclopentadienyl metal compound that can polymerize polyolefins as part of a catalyst system. The monocyclopentadienyl compound can specifically be (C.sub.5 H.sub.4 CH.sub.2 CH.sub.2 NMe.sub.2)TiCl.sub.3.
Claims20
A monocyclopentadienyl metal compound corresponding to the formula:
- ##STR5## Wherein, M is a metal selected from the group consisting of titanium, zirconium, and hafnium;
- m is one, two, or three, depending on the valency and oxidation state of M;
- R' is each independently selected from the group consisting of hydrogen, hydrocarbyl groups, silyl groups, germyl groups, and stannyl groups, including wherein two or more R' groups can be joined to form a ring;
- L is a covalent bridging group containing a main group element from Group 14 selected from the group consisting of carbon, silicon, germanium, and tin;
- E is datively bonded to M, and is a main group element from Group 15 selected from the group consisting of nitrogen, phosphorous, arsenic, and antimony;
- R is independently selected from substituted hydrocarbyl groups, unsubstituted hydrocarbyl groups, and silyl groups, wherein two R-groups can be joined to form a ring, and wherein an R-group and L can be joined to form a ring;
- X is each independently selected from the group consisting of hydrogen, halides, substituted hydrocarbyl groups, unsubstituted hydrocarbyl groups, silyl groups, alkoxides, aryloxides, amides, arylamides, phosphides, arylphosphides, carboxylates, and sulfonates;
- D is a neutral Lewis base;
- and
- n is 0, 1, or 2.
7 more elements
Dependencies are inferred from the claim text.