Butyrolactone-preparation process
AssigneeBASF SE
InventorsMarc Heider, Thomas Ruhl, Jochem Henkelmann, Susanne Stutz, Thomas Preiss, Heinz Rutter, Martin Schafer, Arthur Hohn
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AssigneeBASF SE
InventorsMarc Heider, Thomas Ruhl, Jochem Henkelmann, Susanne Stutz, Thomas Preiss, Heinz Rutter, Martin Schafer, Arthur Hohn
Estimating the term…
A process for the preparation of butyrolactones of the formula I ##STR1## where the substituents R.sup.1 and R.sup.2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert: substituents, is described in which an alkyne of the formula II R.sup.1 --C.tbd.C--R.sup.2 II where the substituents have the meanings indicated above, is reacted under reducing conditions at elevated pressure and elevated temperature with carbon monoxide CO and hydrogen in the presence of a transition metal catalyst or with carbon monoxide and water in the presence of a transition metal catalyst.
A process for the preparation of butyrolactones of the formula I ##STR6## where the substituents R.sup.1 and R.sup.2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert substituents, which comprises reacting an alkyne of the formula II
A process for the preparation of 2-(5H)-furanones of the formula I ##STR7## where the subcstituents R.sup.1 and R.sup.2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl or trialkylsilyl groups, if appropriate carrying inert substituents, which comprises reacting alkynes of the formula II
Dependencies are inferred from the claim text.