Biodegradable and compostable plastic articles, including flat-shaped articles
AssigneeBayer Aktiengesellschaft
InventorsHanns-Peter Muller, Jochen Kalbe, Rainhard Koch
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Abstract
The use of dispersions of polyurethanes containing urea groups and based on selected starting materials, optionally via the intermediate stage of granules obtained by spray drying the dispersions, for the production of fully biodegradable shaped bodies.
Claims5
A method of production of fully biodegradable shaped bodies, including sheet structures, wherein the shaped bodies are made from a polyurethane as its aqueous dispersion or from granules, obtained by spray drying said dispersions, wherein the polyurethane contains urea groups and is the reaction product which is prepared by known methods, observing a ratio of equivalents of isocyanate groups to isocyanate-reactive groups of from 1:1 to 2:1, from
- a) a diisocyanate component consisting of:
- a1) hexamethylene diisocyanate, or
- a2) mixtures of hexamethylene diisocyanate with a total of up to 60% by weight, based on the mixture, of 1-isocyanato-3,3,5-trimethyl-5-isocyanatodicyclohexyl-methane and/or 4,4'diisocyanatodicyclohexylme-thane and/or 1-methyl-2,4(6)diisocyanatocyclohexane, with
- b) a diol component consisting of:
- b1) at least one polyesterdiol with a molecular weight, which can be calculated from the hydroxyl content, of from 500 to 10,000, which is the reaction product of (i) adipic acid and/or succinic acid, and (ii) at least one alkanediol having from 2 to 6 carbon atoms, or
- b2) a mixture of such polyesterdiols with up to 32% by weight, based on the total weight of component b), of alkanediols having from 2 to 6 carbon atoms and which optionally contain ether groups,
- c) a diamine component in a quantity of from 2 to 50 equivalent-%, based on the total quantity of the isocyanate-reactive groups present in components b) and c), consisting of:
- c1) diaminosulfonates of the general formula:
- H.sub.2 N--(--CH.sub.2 --).sub.n --NH--(CH.sub.2 --).sub.m --SO.sub.3 Me
- or
- c2) mixtures of diaminosulfonates c1) with up to 90% by weight, based on the total weight of component c), of ethylenediamine, and, optionally,
- d) hydrophilic polyether alcohols of the general formula:
- H--X--O--R
- in a quantity of up to 10% by weight, based on the total weight of components b), c) and d), and, optionally,
- e) water, which is not included in the calculation of the ratio of equivalents of isocyanate groups to isocyanate-reactive groups,
- wherein in the above mentioned general formulae:
- m and n:
- each independently represent a number from 2 to 6;
- Me:
- represents potassium or sodium;
- R:
- represents a monovalent hydrocarbon radical having 1 to 12 carbon atoms;
- and
- X:
- denotes a polyalkylene oxide chain with a molecular weight in the range of from 88 to 4,000, in which at least 40% of the alkylene oxide units consist of ethylene oxide units, with the balance consisting of propylene oxide units.
Dependencies are inferred from the claim text.