Back to results
US 5,961,770 AGranted
Silicone pressure sensitive adhesives
AssigneeDow Corning Corporation
InventorsMartin Eric Cifuentes, William Neal Fenton
Life of this patent
Estimating the term…
Abstract
The present invention relates to pressure sensitive adhesive compositions which are prepared by heating a mixture of a polydiorganosiloxane, a silicone resin copolymer, and an organic amine compound or metal salt thereof, and then adding an organic peroxide or azo compound to the resultant reaction product. The silicone pressure sensitive adhesives of this invention are useful in preparing articles such as pressure sensitive tapes, labels, emblems and other decorative or informational signs.
Claims20
A method of making an article of manufacture comprising:
- (I) applying a silicone pressure sensitive adhesive composition to at least one surface of a substrate, wherein the silicone pressure sensitive adhesive composition is obtained by a method comprising:
- (i) heating a mixture comprising:
- (A)(i) a hydroxyl-terminated polydiorganosiloxane having a viscosity of from 100 to 10,000,000 mm.sup.2 /s at 25.degree. C. or
- (ii) a mixture of (a) a hydroxyl-terminated polydiorganosiloxane and (b) a polydiorganosiloxane selected from (i) polydiorganosiloxanes terminated with monovalent hydrocarbon radicals free of aliphatic unsaturation or (ii) alkenyl-terminated polydiorganosiloxanes wherein said mixture has a viscosity of from 100 to 10,000,000 mm.sup.2/ s at 25.degree. C.;
- (B) a soluble silicone resin comprising R.sub.3 SiO.sub.1/2 siloxane units and SiO.sub.4/2 units, wherein R is selected from a monovalent hydrocarbon or halohydrocarbon radical free of aliphatic unsaturation and having from 1 to 20 carbon atoms, an alkenyl radical, or a hydroxyl radical;
- and
- (C) an organic amine compound selected from the group consisting of primary amines, secondary amines, and tertiary amines, or a metal salt of an organic amine compound selected from the group consisting of carboxylic acid salts of organic amines and quaternary ammonium salts to form a reaction product having a solids content of at least 70% and a viscosity of up to 200,000 millipascal-seconds at 25.degree.;
- and
- (ii) adding (D) an organic peroxide or azo compound to the reaction product of (i);
- and
- (II) heating the silicone pressure sensitive adhesive composition and the substrate to cure the composition.
8 more elements
Dependencies are inferred from the claim text.