Siloxane MQ resin vesicles and entrapment
AssigneeDow Corning Corporation
InventorsRobert Alan Ekeland, Randal Myron Hill
Life of this patent
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AssigneeDow Corning Corporation
InventorsRobert Alan Ekeland, Randal Myron Hill
Estimating the term…
A method of entrapping a water-soluble substance in vesicles formed from a surface active siloxane is carried out by dissolving the substance to be entrapped in water, adding the surface active siloxane, mildly agitating the mixture, and removing excess water and substance. Water-insoluble substances are entrapped in the vesicles by dissolving the substance to be entrapped in the surface active siloxane, and mildly agitating the substance and the siloxane. The surface active siloxanes consist essentially of tetravalent SiO.sub.2 units, and monovalent R.sub.3 SiO.sub.1/2 and R'R.sub.2 SiO.sub.1/2 units. The ratio of monovalent units to tetravalent units is from 0.4/1 to 2/1, and from 40 to 90% of all monovalent units are R'R.sub.2 SiO.sub.1/2 units. R is a monovalent hydrocarbon group with up to eight carbon atoms, and R' is a polyoxyalkylene group.
A method of entrapping a water-soluble substance in a vesicle formed from a surface active siloxane comprising forming a mixture by dissolving the water-soluble substance to be entrapped in water, adding a surface active siloxane, and agitating the mixture, the surface active siloxane consisting essentially of tetravalent SiO.sub.2 units and monovalent R.sub.3 SiO.sub.1/2 and R'R.sub.2 SiO.sub.1/2 units, the ratio of monovalent units to tetravalent units being from 0.4/1 to 2/1, and from 40 to 90% of all monovalent units being R'R.sub.2 SiO.sub.1/2 units, wherein R denotes a monovalent hydrocarbon group having up to 8 carbon atoms, and R' denotes a polyoxyalkylene group terminated by a hydroxyl group, an alkyl group, an aryl group, or an acyl group.
A method of entrapping a water-insoluble substance in a vesicle formed from a surface active siloxane comprising forming a mixture by combining the water-insoluble substance and a surface active siloxane, and agitating the mixture, the surface active siloxane consisting essentially of tetravalent SiO.sub.2 units and monovalent R.sub.3 SiO.sub.1/2 and R'R.sub.2 SiO.sub.1/2 units, the ratio of monovalent units to tetravalent units being from 0.4/1 to 2/1, and from 40 to 90% of all monovalent units being R'R.sub.2 SiO.sub.1/2 units, wherein R denotes a monovalent hydrocarbon group having up to 8 carbon atoms, and R' denotes a polyoxyalkylene group terminated by a hydroxyl group, an alkyl group, an aryl group, or an acyl group.
A composition comprising a water-soluble substance entrapped in vesicles where the vesicles comprise 1-99.7 percent by weight of a surface active siloxane, and 0.3-99 percent by weight of the water-soluble substance, the surface active siloxane consisting essentially of tetravalent SiO.sub.2 units and monovalent R.sub.3 SiO.sub.1/2 and R'R.sub.2 SiO.sub.1/2 units, the ratio of monovalent units to tetravalent units being from 0.4/1 to 2/1, and from 40 to 90% of all monovalent units being R'R.sub.2 SiO.sub.1/2 units, wherein R denotes a monovalent hydrocarbon group having up to 8 carbon atoms, and R' denotes a polyoxyalkylene group terminated by a hydroxyl group, an alkyl group, an aryl group, or an acyl group.
A composition comprising a water-insoluble substance entrapped in vesicles where the vesicles comprise 1-99.7 percent by weight of a surface active siloxane, and 0.3-99 percent by weight of the water-insoluble substance, the surface active siloxane consisting essentially of tetravalent SiO.sub.2 units and monovalent R.sub.3 SiO.sub.1/2 and R'R.sub.2 SiO.sub.1/2 units, the ratio of monovalent units to tetravalent units being from 0.4/1 to 2/1, and from 40 to 90% of all monovalent units being R'R.sub.2 SiO.sub.1/2 units, wherein R denotes a monovalent hydrocarbon group having up to 8 carbon atoms, and R' denotes a polyoxyalkylene group terminated by a hydroxyl group, an alkyl group, an aryl group, or an acyl group.
Dependencies are inferred from the claim text.