Air separation with intermediate pressure vaporization and expansion
AssigneeAir Products and Chemicals, Inc.
InventorsDonn Michael Herron, Rakesh Agrawal
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Abstract
A double column cryogenic air separation system is operated to increase boilup in the lower pressure column by vaporizing at an intermediate pressure a liquid stream containing at least 20 mole % oxygen, work expanding the stream, and introducing the resulting expanded stream into the lower pressure column. Operation in this mode increases oxygen recovery at a given rate of compressed and purified air feed or reduces the amount air feed required to produce a given rate of oxygen product. Argon recovery can be integrated efficiently with the intermediate pressure vaporization and work expansion steps.
Claims20
In a process for the separation of air in a cryogenic air separation system comprising a higher pressure distillation column and a lower pressure distillation column which is thermally linked with the higher pressure distillation column, wherein air is compressed and purified to remove higher boiling contaminants, at least a portion of the compressed purified air is cooled and distilled in the higher pressure column, at least a portion of the bottoms liquid from the higher pressure column is distilled in the lower pressure column, and at least one nitrogen-enriched stream and at least one oxygen-enriched stream are withdrawn from the system, a portion of the refrigeration required for operation of the air separation system is provided by a method which comprises:
- (a) vaporizing a condensed liquid containing at least about 20 mole % oxygen at a pressure between any pressure in the lower pressure column and any pressure in the higher pressure column to yield an intermediate pressure vapor;
- (b) work expanding the intermediate pressure vapor and introducing the resulting work-expanded stream into the lower pressure column;
- and
- (c) providing the heat for vaporizing the liquid in step (a) by indirect heat exchange with at least a portion of a sidestream vapor withdrawn from the lower pressure column to yield a cooled intermediate stream.
Dependencies are inferred from the claim text.