Polymerization catalyst for alkylene oxide compound and production process of poly(alkylene oxide)
AssigneeMitsui Chemicals, Inc.
InventorsMasahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
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Abstract
A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.
Claims2
A process for the production of a poly(propylene oxide) which comprises reacting a propylene oxide in the presence of (A) an active hydrogen compound selected from the group consisting of (i) polyhydric alcohols having 2 to 10 hydroxyl groups and 2 to 20 carbon atoms, (ii) saccharides or derivatives thereof, and (iii) oligo(alkylene oxide)s or poly(alkylene oxide)s obtained by polymerizing alkylene oxides and said active hydrogen compound
- and (B) a phosphazene compound selected from the group consisting of (i) 1-tert-butyl-2,2,2-tris(dimethylamino)phosphazene, (ii) 1-(1,1,3,3-tetramethylbutyl)-2,2,2-tris(dimethylamino)phosphazene, (iii) 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2.lambda..sup.5 4.lambda..sup.5 -catenadi(phosphazene), (iv) 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bistris(dimethylamino)phosphor anilideneamino!-2.lambda..sup.5,4.lambda..sup.5 -catenadi(phosphazene), (v) 1-(1,1,3,3-tetramethylbutyl)-4,4,4tris(dimethylamino)-2,2-bistris(dimethy lamino)phosphoranilideneamino!-2.lambda..sup.5,4.lambda..sup.5 -catenadi(phosphazene), (vi) 1-tert-butyl-2,2,2-tri(1-pyrrolidinyl)phosphazene, and (vii) 7-ethyl-5,11-dimethyl-1,5,7,11-tetraaza-6.lambda..sup.5 -phosphaspiro5.5!undeca-1(6)-ene,
- or in the presence of a phosphazenium salt of said active hydrogen compound, said phosphazenium salt having been derived from said active hydrogen compound and said phosphazene compound,
- wherein said phosphazene compound or said phosphazenium salt of said active hydrogen compound is in a range of from 1.0.times.10.sup.-7 to 1.0.times.10.sup.-2 mole per mole of propylene oxide, and propylene oxide is in a range of from 2 to 1.0.times.10.sup.5 moles per mole of said coexisting active hydrogen compound when the polymerization is conducted in the presence of said active hydrogen compound and said phosphazene compound or per mole of the sum of said active hydrogen compound forming said phosphazenium salt of said active hydrogen compound and any of said active hydrogen compound which exists in the system, when the polymerization is conducted in the presence of said phosphazenium salt of said active hydrogen compound.
Dependencies are inferred from the claim text.