Mineral or synthetic, hydrogen-based greases, having improved properties
AssigneeAusimont S.p.A.
InventorsPadmanabhan Srinivasan, Laura Montagna, Paolo Savelli, Costante Corti
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Abstract
Greases comprising a mineral and/or synthetic lubricating oil having an hydrogenated basis, a fluoropolyethereal oil and an organic or inorganic thickening agent, wherein the weight ratio lubricating oil+fluoropolyethereal oil/thickening agent ranges from 97:3 to 80:20 and the weight ratio lubricating oil/fluoropolyethereal oil ranges from 95:5 to 60:40.
Claims14
A method for improving the minium working temperature and maximum working temperature of greases containing a lubricating oil selected from the group consisting of a hydrocarbon based mineral oil, an animal oil or vegetable oil, polyesters, polyalphaolefins, silicone, and polyglycols;
- comprising adding thereto a fluoropolyethereal oil and an organic or inorganic thickening agent, the weight ratio of the lubricating oil+fluoropolyethereal oil/thickening agent ranges from 97:3 to 80:20 and the weight ratio of lubricating oil/fluoropolyethereal oil ranges from 95:5 to 60:40, and said fluoropolyethereal oil has a viscosity range from 10 to 4000 cst and are selected from the following structures:
- ##STR6## wherein X is --F, --CF.sub.3 ;
- A' and A are the same or different from each other and are --CF.sub.3, ##STR7## wherein T is H or Cl, the units (CF.sub.2 CF(CF.sub.3)O) and (CFXO) are statistically distributed along the perfluoropolyethereal chain, m and n are integers wherein the ratio of m/n is 20-1000;
- ##STR8## wherein B is CF.sub.3 --C.sub.2 F.sub.5, --C.sub.3 F.sub.7, and m' is a positive integer;
- ##STR9##
- wherein m" is an integer;
- 4. A"OCF.sub.2 CF(CF.sub.3)O!.sub.q' (C.sub.2 F.sub.4 O).sub.s' (CFXO).sub.r' A"'
- wherein A" and A"' are the same or different and are selected from the group consisting of CF.sub.3, C.sub.2 F.sub.5, C.sub.3 F.sub.7 ;
- X is F, CF.sub.3 ;
- r', q' and s' are integers and can be also equal to 0, with the proviso that the viscosity of the perfluoropolyether is within the range indicated above;
- the ratios r'/(r'+s'+q').ltoreq.1/10;
- q'/s' is between 0.2 to 6;
- 5. CF.sub.3 O(C.sub.2 F.sub.4 O).sub.p (CF.sub.2 O).sub.q --CF.sub.3
- wherein p and q are integers which are the same or different and with the proviso that the p/q ratio is comprised between 0.1 and 5 and such that the viscosity is within the limits above indicated;
- 6. A.sup.iv O--CF.sub.2 CF.sub.2 CF.sub.2 O).sub.m"' A.sup.v
- wherein A.sup.iv and A.sup.v, are the same or different and are selected from the group consisting of C.sub.2 F.sub.5, C.sub.3 F.sub.7 and m"' is an integer;
- 7. DO--(CF.sub.2 --CF.sub.2 O).sub.r D'
- wherein D and D' are the same or different and are selected from the group consisting of CF.sub.3, C.sub.2 F.sub.5, and r is an integer;
- ##STR10## wherein R'.sub.f is a perfluoroalkyl, R.sub.f is F or a perfluoroalkyl, n' is an interger.
Dependencies are inferred from the claim text.