Dyes, processes for their preparation and their use

A dye of the formula ##STR204## in which A.sub.1 and A.sub.2 independently of one another are radicals of the formulae ##STR205## in which R.sub.10 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, ##STR206## in which R.sub.10 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, ##STR207## in which R.sub.10 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, ##STR208## in which R.sub.11 is 0 to 4 identical or different substituents selected from halogen, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, amino, acetylamino, ureido, hydroxyl, carboxyl, sulfomethyl and sulfo, ##STR209## in which R.sub.12 is C.sub.1 -C.sub.4 alkanoyl, benzoyl or a halogenotriazinyl radical which is unsubstituted or further substituted, ##STR210## in which R.sub.12 is C.sub.1 -C.sub.4 alkanoyl, benzoyl or a halogenotriazinyl radical which is unsubstituted or further substituted, ##STR211## in which R.sub.13 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, ##STR212## in which R.sub.14 and R.sub.16 independently of one another are hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl, and

• R.sub.15 is hydrogen, cyano, carbamoyl or sulfomethyl, ##STR213## in which R.sub.13 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, ##STR214## in which R.sub.17 is 0 to 2 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo;
• and
• Z' is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl, ##STR215## in which R.sub.18 is 0 to 2 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo;
• and
• Z' is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl, ##STR216## in which R.sub.10 is 0 to 3 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo,
• R.sub.10 ' is 0 to 2 identical or different substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, C.sub.1 -C.sub.4 hydroxyalkoxy or C.sub.1 -C.sub.4 sulfatoalkoxy,
• R.sub.11 is 0 to 3 identical or different substituents selected from halogen, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, amino, acetylamino, ureido, hydroxyl, carboxyl, sulfomethyl and sulfo and
• R.sub.19 is hydrogen or a radical of the formula --SO.sub.2 Z', --NH--CO--(CH.sub.3).sub.2-3 --SO.sub.2 Z', --NH--CO--C(Hal).dbd.CH.sub.2 or --NH--CO--CH(Hal)--CH.sub.2 --Hal, in which
• Z' is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl and Hal is halogen, ##STR217## in which the benzene nuclei contain no further substituents or are further substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylsulfonyl, halogen or carboxyl, ##STR218## in which Pc is a radical of a metal phthalocyanine;
• W' is --OH and/or --NR.sub.9 R.sub.9 ';
• R.sub.9 and R.sub.9 ' independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by hydroxyl or sulfo;
• R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl;
• E' is a phenylene radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, halogen, carboxyl or sulfo, or a C.sub.2 -C.sub.6 alkylene radical;
• and
• k is 1 to 3, ##STR219## in which E' is a phenylene radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, halogen, carboxyl or sulfo, or a C.sub.2 -C.sub.6 alkylene radical;
• and
• the outer benzene rings in formula (10) contain no further substituents or are further substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, acetylamino, nitro, halogen, carboxyl, sulfo or --SO.sub.2 --Z', in which
• Z' is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl or ##STR220## in which G is a phenylene, cyclohexylene, phenylenemethylene or C.sub.2 -C.sub.6 alkylene radical,
• where the anthraquinone nucleus contains no further substituents or is substituted by a further sulfo group and a phenyl radical G is substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl or sulfo,
• R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,
• Y.sub.1 and Y.sub.2 independently of one another are fluorine or chlorine and
• n is the number 2 or 3.