Quenching post cure
AssigneeDow Corning Corporation
InventorShizhong Zhang
Life of this patent
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Abstract
A method of thickening solvents involves reacting (A) an .tbd.Si--H containing polysiloxane with (B) an alpha, omegadiene; conducting the reaction in the presence of a platinum catalyst and (C) a solvent; continuing the reaction until a gel is formed by crosslinking and addition of .tbd.Si--H across double bonds in the alpha, omega-diene; adding additional solvent and a post cure quenching agent to the gel; and subjecting the solvent, the post cure quenching agent, and the gel to shear force until a paste is formed.
Claims2
A method of thickening solvents comprising reacting (A) an .tbd.Si--H containing polysiloxane of formula R.sub.3 SiO(R'.sub.2 SiO).sub.a (R"HSiO).sub.b SiR.sub.3 and optionally an .tbd.Si--H containing polysiloxane of formula HR.sub.2 SiO(R'.sub.2 SiO).sub.c SiR.sub.2 H or formula HR.sub.2 SiO(R'.sub.2 SiO).sub.a (R"HSiO).sub.b SiR.sub.2 H where R, R', and R" are alkyl groups of 1-6 carbon atoms;
- a is 0-250;
- b is 1-250;
- and c is 0-250;
- with (B) an alpha, omega-diene of formula CH.sub.2 .dbd.CH(CH.sub.2).sub.x CH.dbd.CH.sub.2 where x is 1-20;
- conducting the reaction in the presence of a platinum catalyst and (C) a solvent selected from the group consisting of (i) organic compounds, (ii) compounds containing a silicon atom, (iii) mixtures of organic compounds, (iv) mixtures of compounds containing a silicon atom, and (v) mixtures of organic compounds and compounds containing a silicon atom;
- continuing the reaction until a gel is formed by crosslinking and addition of .tbd.Si--H across double bonds in the alpha, omega-diene;
- adding additional solvent and a post cure quenching agent to the gel;
- and subjecting the solvent, the post cure quenching agent, and the gel to shear force until a paste is formed;
- the post cure quenching agent being selected from the group consisting of vinyl-t-butyldimethylsilane, vinyldiethylmethylsilane, vinylethyldimethylsilane, vinyltriethylsilane, vinyltrimethylsilane, divinyldimethylsilane, divinyltetramethyldisilane, vinylpentamethyldisiloxane, 1,3-divinyltetramethyldisiloxane, vinyltrisiloxane (CH.sub.3).sub.3 SiOSi(CH.dbd.CH.sub.2)(CH.sub.3)OSi(CH.sub.3).sub.3, 1,5-divinylhexamethyltrisiloxane, and divinylsiloxane oligomer (CH.sub.2 .dbd.CH)Me.sub.2 SiO(Me.sub.2 SiO).sub.8 SiMe.sub.2 (CH.dbd.CH.sub.2).
Dependencies are inferred from the claim text.