Back to results
US 5,925,715 AGranted
Photocurable ionomer cement systems
AssigneeMinnesota Mining and Manufacturing Company
InventorSumita B. Mitra
Life of this patent
Estimating the term…
Abstract
A dental cement system containing a photocurable ionomer, reactive powder and water undergoes both a conventional setting reaction and a photocuring reaction. The cement system can provide a long working time and can be cured on demand by exposure to an appropriate source of radiant energy. The surface of the cement cured in this manner is then hard enough to allow subsequent clinical procedures to be performed, while the ongoing chemical-cure "setting" reaction hardens the remainder of the cement.
Claims4
A photocurable ionomer of the formula
- B(X).sub.m (Y).sub.n
- wherein
- B represents an organic backbone;
- each X independently is an ionic group capable of undergoing a setting reaction in the presence of water and a reactive powder,
- each Y independently is a photocurable group selected from the group consisting of free radically photocurable ethylenically unsatureated groups, cationically photocurable vinyl ether groups and cationically photocurable epoxy groups,
- m is a number having an average value of 2 or more, and
- n is a number having an average value of 1 or more,
- wherein at least one of said Y groups is linked to said backbone by means of an amide linkage formed by reacting an X group of the formula --COOH of a polymer of the formula B(X).sub.m+n with a coupling compound containing both said Y group and a group of the formula --NCO capable of reacting with said X group.
5 more elements
A photocurable ionomer of the formula
- B(X).sub.m (Y).sub.n
- wherein
- B represents an organic backbone;
- each X independently is an ionic group capable of undergoing a setting reaction in the presence of water and a reactive powder,
- each Y independently is a photocurable group selected from the group consisting of free radically photocurable ethylencially unsatureated groups, cationically photocurable vinyl ether groups and cationically photocurable epoxy groups,
- m is a number having an average value of 2 or more, and
- n is a number having an average value of 1 or more,
- wherein substantially all of said Y groups are linked to said backbone by means of an amide linkage formed by reacting an X group of the formula --COOH of a polymer of the formula B(X).sub.m+n with a coupling compound containing both said Y group and a group of the formula --NCO capable of reacting with said X group,
- wherein said Y group linked by means of an amide linkage is the same as the Y group that is derived from the reaction of a polymer of the formula B(X).sub.m+n with a coupling compound selected from the group consisting of allyl isocyanate, 2-isocyanatoethyl methacrylate, ##STR7## wherein p is 1 to 20 and R is H or lower alkyl (e.g., having 1 to 6 carbon atoms), ##STR8## wherein q is 1 to 18, ##STR9## wherein q is as defined above, ##STR10## and their corresponding acrylates.
6 more elements
Dependencies are inferred from the claim text.