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US 5,919,273 AGranted
Compositions and processes for dyeing keratin fibers with an oxidation base, a coupler, a cationic direct dye, and an oxidizing agent
AssigneeL'oreal
InventorsChristine Rondeau, Jean Cotteret, Roland de la Mettrie
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Abstract
A ready-to-use composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair, comprising at least one oxidation base in combination with at least one coupler of substituted meta-aminophenol type, at least one cationic direct dye and at least one oxidizing agent, as well as to the dyeing process using this composition.
Claims43
A ready-to-use composition for the oxidation dyeing of keratin fibers, comprising, in a medium suitable for dyeing:
- at least one oxidation base,
- at least one coupler selected from meta-aminophenols of formula (I), or the acid-addition salts thereof:
- ##STR10## in which:
- R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 monohydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl radical,
- R.sub.2 represents a hydrogen atom, a C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy radical or a halogen atom,
- R.sub.3 represents a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 monohydroxyalkyl, C.sub.2 -C.sub.4 polyhydroxyalkyl, C.sub.1 -C.sub.4 mono-hydroxyalkoxy or C.sub.2 -C.sub.4 polyhydroxyalkoxy radical,
- at least one cationic direct dye selected from compounds of formula (II):
- ##STR11## in which:
- D independently represents a nitrogen atom or a --CH group,
- R.sub.4 and R.sub.5 each independently represents a hydrogen atom;
- a C.sub.1 -C.sub.4 alkyl radical which may be substituted with a --CN, --OH or --NH.sub.2 radical or form, with a carbon atom of the benzene ring, a heterocycle which is optionally oxygenated or nitrogenous, which may be substituted with one or more C.sub.1 -C.sub.4 alkyl radicals;
- or a 4'-aminophenyl radical,
- R.sub.6 represents a hydrogen or halogen atom, or a C.sub.1 -C.sub.4 alkoxy or acetyloxy radical,
- X.sup.- represents an anion selected from chloride, methylsulphate or acetate, and
- A represents a group selected from the following structures:
- ##STR12## in which:
- R.sub.7 represents a C.sub.1 -C.sub.4 alkyl radical which may be substituted with a hydroxyl radical, and
- R.sub.8 represents a C.sub.1 -C.sub.4 alkoxy radical,
- with the proviso that when D represents --CH, A represents A.sub.4 or A.sub.13 and R.sub.6 is other than an alkoxy radical, then R.sub.4 and R.sub.5 do not simultaneously denote a hydrogen atom;
- and
- at least one oxidizing agent.
18 more elements
Dependencies are inferred from the claim text.