Aromatic alkylation process
AssigneeFina Technology, Inc.
InventorAshim Kumar Ghosh
Life of this patent
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Abstract
A process for the alkylation of an aromatic substrate over a molecular sieve zeolite catalyst involving supplying an aromatic substrate to a reaction zone containing the catalyst. The molecular sieve catalyst is an effective aromatic alkylation catalyst and comprises a modified zeolite beta alkylation catalyst having an intergrowth of a ZSM-12 crystalline framework within the crystalline framework of zeolite beta. An alkylating agent is also supplied to the reaction zone which is operated under temperature and pressure conditions effective to cause alkylation of the aromatic substrate by the alkylating agent. An alkylated substrate is recovered from the reaction zone.
Claims22
In a method for the alkylation of an aromatic compound, the steps comprising:
- (a) supplying a feed stock containing an aromatic substrate into a reaction zone and into contact with a molecular sieve catalyst comprising a modified zeolite beta alkylation catalyst having an intergrowth of a ZSM-12 crystalline framework within the crystalline framework of zeolite beta;
- (b) supplying an alkylating agent to said reaction zone;
- (c) operating said reaction zone at temperature and pressure conditions effective to affect alkylation to said aromatic substrate by said alkylating agent;
- and
- (d) recovering alkylated aromatic substrate from said reaction zone.
In a method for the production of ethyl benzene by the liquid phase ethylation of benzene, the steps comprising:
- (a) supplying a benzene containing feed stock into a reaction zone containing a molecular sieve alkylation catalyst comprising a modified zeolite beta alkylation catalyst having an intergrowth of a ZSM-12 crystalline framework with the crystalline framework of zeolite beta;
- (b) supplying an ethylating agent to said reaction zone;
- (c) operating said reaction zones at temperature and pressure conditions to maintain said benzene in the liquid phase to cause monoethylation of said benzene in the liquid phase in the presence of said catalyst and under conditions in which xylene produced in said reaction zone is no more than 0.05 wt. % based upon the amount of ethyl benzene produced;
- and
- (d) recovering ethyl benzene from said reaction zone.
In a method for the production of ethyl benzene by the liquid phase ethylation of benzene, the steps comprising:
- (a) supplying a benzene containing feed stock into a reaction zone containing a molecular sieve alkylation catalyst characterized by an x-ray diffraction pattern characteristic of zeolite beta and having a maximum peak at an interplanar spacing D of 4.0/.+-.0.1A and secondary peaks S.sub.1 at a D spacing of 11.4.+-.0.2A, S.sub.2 at a D spacing of 4.2.+-.0.1A and a secondary doublet S.sub.3, S.sub.4 at D spacings within the range of about 3.0-3.4.+-.0.1A, and further comprising a first secondary peak characteristic of ZSM-12 occurring at an interplanar spacing D 10.0.+-.2A and additional secondary peaks characteristic of ZSM-12 at D spacings less than the D spacing of said primary peak but greater than the D spacing of said doublet S.sub.3, S.sub.4 ;
- (b) supplying an ethylene agent to said reaction zone;
- (c) operating said reaction zones at temperature and pressure conditions to maintain said benzene in the liquid phase to cause monoethylation of said benzene in the liquid phase in the presence of said catalyst;
- and
- (d) recovering ethyl benzene from said reaction zone.
Dependencies are inferred from the claim text.