Semifluorinated side chain-containing polymers
AssigneeCornell Research Foundation, Inc.
InventorsChristopher K. Ober, Jianguo Wang, Edward J. Kramer
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AssigneeCornell Research Foundation, Inc.
InventorsChristopher K. Ober, Jianguo Wang, Edward J. Kramer
Estimating the term…
Fluorinated polymers for use per se or in a blend with compatible homopolymer or copolymer which is not fluorinated, for providing a low surface energy (anti-stick, non-wetting, low friction) surface which is stable on immersion in water, has a weight average molecular weight ranging from 10.sup.3 to 10.sup.6 and comprises backbone containing (a) methylene groups and (b) side chain bearing groups with side chain on each side chain bearing group having the formula --Q--(CF.sub.2).sub.q F wherein Q comprises alkylene moiety and wherein the fluoroalkyl group attached to Q is spaced by r atoms from the atom in the backbone to which Q is attached, wherein q ranges from 6 to 15, r ranges from 6 to 18, and the ratio of q to r ranges from 0.6:1 to 1.8:1. Preferred fluorinated polymers include semifluorinated block copolymers of modified isoprene and styrene and semifluorinated ionenes.
Fluorinated polymer for providing a low surface energy surface which is stable on immersion in water, said fluorinated polymer having a weight average molecular weight ranging from about 1.times.10.sup.3 to about 1.times.10.sup.6 and not containing moiety bearing a charge and comprising backbone containing (a) methylene groups and (b) side chain bearing groups ##STR15## where C is a backbone atom and R is selected from the group consisting of hydrogen and alkyl containing 1 to 6 carbon atoms, and side chain on each side chain bearing group, said side chain having the formula --R'--O--C(O)--(CH.sub.2).sub.p-1 --(CF.sub.2).sub.q F where R' is alkylene or isoalkylene containing 1 to 10 carbon atoms and the fluoroalkyl group of said side chain is spaced by r atoms from atom of the backbone to which R' is attached, wherein q ranges from 6 to 15, r ranges from 6 to 18, p is r minus 1 minus the number of chain atoms in R', and the ratio of q to r ranges from 0.6:1 to 1.8:1.
Dependencies are inferred from the claim text.