Use of infrared spectroscopy to produce high lubricity, high stability, Fischer-Tropsch diesel fuels and blend stocks
OwnerBruce Randall Cook, Paul Joseph Berlowitz +1inventors
InventorsBruce Randall Cook, Paul Joseph Berlowitz, Rebecca Lynn Rucker
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Abstract
The present invention is a method for controlling a process for producing a distillate fuel heavier than gasoline. The process includes several different fractions, streams, including alcohols, olefins, and acids. At least one of the streams is irradiated with IR radiation, allowing the determination of the concentrations of at least one of alcohols, olefins and acids. The temperature of the separator is then adjusted to change the concentrations to pre-determined values.
Claims9
A method for controlling a process for producing a distillate fuel heavier than gasoline comprising:
- (a) separating the product of a Fischer-Tropsch process into a heavier fraction and a lighter fraction,
- (b) further separating the lighter fractions using a temperature separator into at least two fractions, (i) at least one fraction including alcohols and (ii) at least one fraction including olefins and acids,
- (c) irradiating said fraction (i) with IR radiation,
- (d) measuring the absorption spectrum of said IR radiation,
- (e) determining a number representative of the concentrations of at least one of alcohols, olefins and acids in said fraction (i),
- (f) adjusting said temperature of said separator in response to said concentrations to change said concentrations to predetermined values,
- (g) hydroisomerizing at least a portion of the heavier fractions (a) and at least a portion of the (b) (ii) fractions at hydroisomerization conditions and recovering the hydroisomerization product, and
- (h) blending at least a portion of the fraction of (b) (i) with at least at portion of the hydroisomerization product.
A method for controlling a process for producing a distillate fuel heavier than gasoline comprising:
- (a) separating the product of a Fischer-Tropsch process into a heavier fraction and a lighter fraction,
- (b) further separating the lighter fractions using a temperature separator into at least two fractions, (i) at least one fraction containing alcohols and (ii) at least one fraction containing olefins and acids,
- (c) hydroisomerizing at least a portion of the heavier fractions (a) and at least a portion of the (b) (ii) fractions at hydroisomerization conditions and recovering the hydroisomerization product,
- (d) blending at least a portion of the fraction of (b) (i) with at least a portion of the hydroisomerization product to produce a blended stream,
- (e) irradiating said blended stream of (d) with IR radiation,
- (f) measuring the absorption spectrum of said IR radiation,
- (g) determining a number representative of at least one of the concentrations of said alcohols, olefins, and said acids, and
- (h) adjusting said temperature of said separator in response to said concentrations to change said concentrations to pre-determined values.
A method for controlling a process for producing a distillate fuel heavier than gasoline comprising:
- (a) separating the product of a Fischer-Tropsch process into a heavier fraction and a lighter fraction,
- (b) further separating the lighter fractions using a temperature separator into at least two fractions, (i) at least one fraction including alcohols and (ii) at least one fraction including olefins and acids,
- (c) hydroisomerizing at least a portion of the heavier fractions (a) and at least a portion of the (b) (ii) fractions at hydroisomerization conditions and recovering the hydroisomerization product,
- (d) blending at least a portion of the fraction of (b) (i) with at least a portion of the hydroisomerization product to produce a blended stream,
- (e) fractionating said blended stream and recovering a distillate product,
- (f) irradiating said distillate product with IR radiation,
- (g) measuring the absorption spectrum of said IR radiation,
- (h) determining a number representative of the concentrations of at least one of alcohols, olefins, and acids in said distillate product, and
- (i) adjusting said temperature of said separator in response to said concentrations to change said concentrations to pre-determined values.
Dependencies are inferred from the claim text.