US 5,891,358 A · Liquid crystal mixtures and devices

Abstract

The invention describes liquid crystal compounds of formula (I) which are suitable for use in liquid crystal devices including those devices which exploit the electroclinic effect, ##STR1## where X may be CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy; X.sub.2 may be CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy; X.sub.3 may be CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen; X.sub.4 may be CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen; provided that at lease one of X or X.sub.2 is CF.sub.3, CF.sub.2 H, CFH.sub.2, CN, NO.sub.2 or halogen; A and B are independently phenyl, mono-fluorinated phenyl, di-fluorinated phenyl or cyclohexyl; Y may be single bond, COO, OOC, C.dbd.C; q may be 0 or 1; R.sub.1 may be an end group of formula (II) wherein Z may be a single bond, O, CO.sub.2, (CH.sub.2).sub.n or (CH.sub.2).sub.n O where n may be 1 or 2; J and M may be independently H, C.sub.1-4 alkyl; W may be C.sub.1 -C.sub.12 straight or branched alkyl chain; R.sub.2 may contain 1-14 carbon atoms wherein one or more non-adjacent CH.sub.2 groups may be replaced by CO.sub.2 or O. X or X.sub.2 may give rise to steric hindrance with the nearest terminal group. The materials of the current invention may be mixed together and/or with other liquid crystal compounds. Suitable devices which the materials of the present invention may be incorporated in include beam steerers, piezoelectric actuators or sensors and pyroelectric sensors and displays in general. The materials of the present invention may also be useful as dopants in ferroelectrics and as second order non-linear optic materials for second harmonic conversion of light.

Claims10

Dependent claims

An electroclinic device comprising two spaced cell walls each bearing electrode structures and treated on at least one facing surface with an alignment layer, a layer of a smectic liquid crystal material enclosed between the cell walls, wherein the liquid crystal material contains one or more of the compounds described by formula I:

##STR34## wherein X is CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy;
X.sub.2 is CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy;
X.sub.3 is CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen;
X.sub.4 is CN, NO.sub.2, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen;
provided that at least one of X or X.sub.2 is CF.sub.3, CF.sub.2 H, CFH.sub.2, CN, NO.sub.2 or halogen;
A and B are independently phenyl, mono-fluorinated phenyl, di-fluorinated phenyl or cyclohexyl;
Y is a single bond or COO or OOC or C.tbd.C;
q is 0 or 1;
R.sub.1 is an end group of Formula II:
##STR35## wherein Z is a single bond or O or CO.sub.2 or (CH.sub.2).sub.n or CH.sub.2).sub.n O where n may be 1 or 2;
J and M are independently selected from H and C.sub.1-4 alkyl;
W is C.sub.1 -C.sub.12 straight or branched alkyl chain;
and
R.sub.2 contains 1-14 carbon atoms wherein one or more non-adjacent CH.sub.2 groups may be replaced by CO.sub.2 or O;
and when at least one of X or X.sub.2 is halogen then q is 1 and Y is not a single bond and the compound of Formula I possesses a chiral center.

12 more elements

A non-linear optic device comprising two spaced cell walls, treated on at least one facing surface with an alignment layer, a layer of a smectic liquid crystal material enclosed between the cell walls, wherein the liquid crystal material contains one or more compounds of Formula I:

##STR38## wherein X is CN, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy;
X.sub.2 is CN, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, hydrogen, alkyl or alkoxy;
X.sub.3 is CN, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen;
X.sub.4 is CN, CF.sub.3, CF.sub.2 H, CFH.sub.2, halogen, alkyl, alkoxy or hydrogen;
provided that at least one of X or X.sub.2 is CF.sub.3, CF.sub.2 H, CFH.sub.2, CN, or halogen;
A and B are independently phenyl, mono-fluorinated phenyl, di-fluorinated phenyl or cyclohexyl;
Y is a single bond or COO or OOC or C.tbd.C;
q is 0 or 1;
R.sub.1 is an end group of formula II:
##STR39## wherein Z is a single bond or O or CO.sub.2 or (CH.sub.2).sub.n or (CH.sub.2).sub.n O where n may be 1 or 2;
J and M are independently selected from H and C.sub.1-4 alkyl;
W is C.sub.1 -C.sub.12 straight or branched alkyl chain;
R.sub.2 contains 1-14 carbon atoms wherein one or more non-adjacent CH.sub.2 groups may be replaced by CO.sub.2 or O;
and further provided that at least one of the following criteria is met:
(i) q=0;
(ii) Y is C.tbd.C;
and
(iii) X, X.sub.2, X.sub.3, and X.sub.4 are selected from CF.sub.3, CF.sub.2 H, CFH.sub.2, CN, halogen, alkyl or alkoxy such that any one of the following substitution patterns may be present:
(iv) X
(v) X.sub.2
(vi) X.sub.2 and X
(vii) X and X.sub.3
(viii) X.sub.2 and X.sub.4
(ix) X and X.sub.3 and X.sub.4 or
X and X.sub.2 and X.sub.4.

22 more elements

Dependencies are inferred from the claim text.

Liquid crystal mixtures and devices

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Liquid crystal mixtures and devices

Life of this patent

Abstract

Claims10