Alkyl-containing porous resin, process for its preparation and its use

A process for preparing an alkyl-containing porous resin with a specific surface area of 50 to 600 m.sup.2 /g, the process comprising the steps of mixing a monomer mixture of, based on the total weight of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 50% by weight of a vinylbenzyloxyalkane derivative represented by the formula ##STR4## wherein n is an integer of 1 to 18, with an organic solvent which does not participate in polymerization, is sparingly soluble in water, is capable of solving the monomer mixture but is incapable of solving the resulting copolymer, and subjecting the obtained solution to suspension polymerization in an aqueous medium using a radical polymerization initiator.

A process for preparing an alkyl-containing porous resin with a specific surface area of 50 to 600 m.sup.2 /g, the process comprising the steps of mixing together a monomer mixture of, based on the total weight of the monomers, 15 to 97% by weight of divinylbenzene, 0 to 82% by weight of at least one aromatic monovinyl monomer selected from the group consisting of styrene, methylstyrene and ethylvinylbenzene and 3 to 50% by weight of a vinylbenzyloxyalkane derivative represented by the formula ##STR5## wherein n is an integer of 1 to 18, a radical polymerization initiator, an organic solvent which does not participate in polymerization, is sparingly soluble in water, is capable of solving the monomer mixture but is incapable of solving the resulting copolymer, dispersing under an elevated pressure the obtained organic phase into an aqueous phase containing an anionic or nonionic surfactant through a porous glass membrane having a uniform pore diameter to disperse the organic phase, and subjecting the dispersion to suspension polymerization.