Process for manufacturing aqueous compositions comprising peracids
AssigneeThe Procter & Gamble Company
InventorsGiulia Ottavia Bianchetti, Stefano Scialla, Sandro Campestrini, Fulvio Di Furia
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Abstract
A process for manufacturing an aqueous composition of a peracid by reacting an acid anhydride with concentrated hydrogen peroxide. Preferably the aqueous peracid composition is further converted into an emulsion having improved stability wherein said emulsion contains a surfactant having an HLB above 11 and a surfactant having an HLB below 11.
Claims4
A process for manufacturing an aqueous composition comprising a peracid, or mixture thereof, wherein said peracid is emulsified in a surfactant system comprising at least a hydrophilic surfactant having an HLB a bove 11, and a hydrophobic surfactant having an HLB below 11, said process comprising the steps of:
- 1--preparing an aqueous peracid-comprising composition by a process which comprises the step of forming said peracid by reacting the corresponding anhydride with a solution of hydrogen peroxide comprising at least about 3 moles of said hydrogen peroxide per molar equivalent of said corresponding anhydride, wherein said corresponding anhydride is selected from anhydrides having the following formula:
- ##STR4## wherein R.sub.1 and R.sub.2 are linear or branched alkyl groups having of from 1 to about 20 carbon atoms, said anhydrides being symmetric anhydrides or asymmetric anhydrides;
- -- preparing a hydrophobic mixture which comprises at least said hydrophobic surfactant;
- 3--preparing a hydrophilic mixture which comprises at least water and said hydrophilic surfactant;
- 4--mixing the composition obtained in step 1 in said hydrophilic mixture if said corresponding anhydride used in step 1 is an anhydride having the following formula:
- ##STR5## wherein R.sub.1 and R.sub.2 are linear or branched alkyl groups having of from 1 to 4 carbon atoms, said anhydrides being symmetric anhydrides or asymmetric anhydrides or in said hydrophobic mixture if said corresponding anhydride used in step 1 is an anhydride having the following formula:
- ##STR6## wherein R.sub.1 and R.sub.2 are linear or branched alkyl groups having of from 5 to about 20 carbon atoms, said anhydrides being symmetric anhydrides or asymmetric anhydrides
- -- then mixing together said hydrophobic mixture and said hydrophilic mixture, and wherein steps 2 and 3 may be performed in any order.
Dependencies are inferred from the claim text.