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US 5,863,513 AGranted
Treatment of gas
AssigneeThe BOC Group, Inc.
InventorThomas Rathbone
Life of this patent
Estimating the term…
Abstract
An elevated pressure nitrogen stream from an air separation plant is used to provide cooling for one or more sulphur condensers in an oxygen-enhanced Claus process for recovering sulphur.
Claims8
A method of recovering sulphur from a feed gas stream comprising hydrogen sulphide, comprising:
- separating air into an oxygen product stream and a nitrogen product stream;
- reacting at least part of the oxygen product stream with some of the hydrogen sulphide content of the feed gas in one or more furnaces to form sulphur dioxide and water vapour, and then allowing the so-formed sulphur dioxide to react with hydrogen sulphide in the furnace or furnaces to form a hot gas stream comprising unreacted hydrogen sulphide and sulphur dioxide, sulphur vapour and water vapour;
- condensing sulphur from the hot gas stream by indirectly exchanging heat between at least some of the product nitrogen stream at a pressure of at least 2 atmospheres and the hot gas stream;
- expanding the at least some of the product nitrogen stream in a first turbine with useful work being recovered from the first turbine;
- downstream of the first turbine, recompressing the at least some of the nitrogen product stream to at least two atmospheres;
- condensing further sulphur from the hot gas stream by indirectly exchanging the heat between the at least some of the nitrogen product stream with the hot gas stream;
- and expanding the at least some of the nitrogen product stream in a second turbine with the recovery of useful work.
4 more elements
An apparatus for recovering sulphur from a feed gas comprising hydrogen sulphide, including:
- air separation means for producing an oxygen product stream and a nitrogen product stream;
- at least one furnace for reacting at least part of the oxygen product stream with a part of the hydrogen sulphide content of the feed gas to form water vapour and sulphur dioxide, and for then allowing so formed sulphur dioxide to react with hydrogen sulphide to form a hot gas stream comprising sulphur vapour, water vapour and residual sulphur dioxide and hydrogen sulphide;
- at least one condenser for condensing sulphur from the hot gas stream including means for indirectly exchanging heat between at least part of the nitrogen product stream at a pressure of at least 2 atmospheres and the hot gas stream downstream of the at least one furnace;
- a first turbine for expanding the thus heated at least part of the nitrogen product stream;
- first means for recovering work from the expansion of the at least part of the nitrogen product stream;
- a compressor for recompressing the thus expanded at least part of the nitrogen product stream to at least 2 atmospheres;
- condenser means for condensing sulphur from the hot gas stream including further means for indirectly exchanging heat between said at least part of the nitrogen product stream with the hot gas stream downstream of the compressor;
- a second turbine for expanding the thus re-heated said at least part of the nitrogen product stream;
- and second means for recovering work from the expansion of the at least part of the nitrogen product stream.
6 more elements
Dependencies are inferred from the claim text.