Process for the hydrogenation of esters of unsaturated fatty acids
AssigneeBayer Aktiengesellschaft
InventorGerhard Darsow
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AssigneeBayer Aktiengesellschaft
InventorGerhard Darsow
Estimating the term…
Esters of unsaturated fatty acids or mixtures thereof can be hydrogenated by a catalysed liquid-phase hydrogenation with hydrogen to give saturated or partially saturated esters of fatty acids or ester mixtures of fatty acids by carrying out the hydrogenation continuously at a pressure of 50 to 350 bar and a reaction temperature of 40 to 150.degree. C. on oxygen-free and support-free shaped bodies which are arranged in a fixed bed and made of pressed powders of elements of the iron subgroup of subgroup VIII of the Periodic Table of the Elements or their alloys with each other or their alloys with elements of subgroup VI; in addition, hydrogenation-inert elements can be present. The shaped bodies have a compressive strength of 20 to 250N on the curved shaped body surface and have an internal surface area of 10 to 90 m.sup.2 /g.
A process for the continuous preparation of esters of partially or completely saturated fatty acids or mixtures of a plurality thereof by catalytic hydrogenation of esters of unsaturated fatty acids or mixtures of a plurality thereof, where the acid moiety of the esters contains 6 to 30 C atoms and the alcohol moiety is monohydric to trihydric and contains 1 to 20 C atoms, wherein the hydrogenation is carried out in a hydrogenation reactor in the liquid phase at an H.sub.2 pressure of 50 to 350 bar, at a 20 to 60-times molar amount of H.sub.2, based on the stoichiometric amount and at a temperature of 40.degree. to 150.degree. C. on oxygen-free and support-free catalysts arranged in a fixed bed which are present as pressed shaped bodies produced from metal powders or particles which have a compressive strength of 20 to 250N on the curved shaped body surface and an internal surface area of 10 to 90 m.sup.2 /g and in which the metal powders contain 65 to 100% by weight of one or more ferrous metals, 0 to 15% by weight of one or more metals of subgroup VI and 0 to 20% by weight of one or more hydrogenation-inert elements selected from the group consisting of aluminium, silicon, titanium and carbon, all based on the total weight of the metal powder or particles.
Dependencies are inferred from the claim text.