Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
AssigneeArco Chemical Technology, L.P.
InventorsAndrew P. Kahn, Anne M. Gaffney
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Abstract
Direct oxidation of propylene to propylene oxide is accomplished using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters. In one embodiment of the invention, the tungsten promoter and the potassium promoter are simultaneously introduced through the use of potassium tungstate. Catalysts of this type exhibit unusually high propylene oxide productivity when carbon dioxide is present in the feedstream.
Claims13
A process for propylene epoxidation comprising contacting a feedstream comprising propylene, oxygen, carbon dioxide, a nitrogen oxide species and an organic halide at a temperature of from 200.degree. C. to 300.degree. C. with a supported silver catalyst comprised of:
- (a) a support comprised of calcium carbonate wherein calcium carbonate constitutes at least 25 percent by weight of the supported silver catalyst;
- (b) from 10 to 60 weight percent Ag;
- (c) from 0.5 to 7 weight percent W derived from a tungsten compound comprised of a tungsten oxyanion;
- and
- (d) from 0.5 to 5 weight percent K derived from a potassium salt selected from the group consisting of potassium carbonate, potassium bicarbonate, potassium nitrate, potassium nitrite, potassium tungstate, and mixtures thereof.
A process for propylene epoxidation comprising contacting a feedstream comprised of propylene, oxygen, carbon dioxide, NO and an alkyl chloride at a temperature of from 200 to 300.degree. C. with a supported silver catalyst comprised of
- (a) a support consisting essentially of calcium carbonate;
- (b) from 10 to 60 weight percent Ag;
- (c) from 0.5 to 7 weight percent W derived from a tungsten compound selected from the group consisting of ammonium paratungstate, sodium tungstate, potassium tungstate and mixtures thereof;
- and
- (d) from 1 to 3 weight percent K derived from a potassium salt selected from the group consisting of potassium carbonate, potassium bicarbonate, potassium nitrate, potassium nitrite, potassium tungstate and mixtures thereof,
- wherein said supported silver catalyst is essentially free of rhenium.
Dependencies are inferred from the claim text.