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US 5,859,063 AGranted
Use of certain N-acetonylbenzamides as fungicides
AssigneeRohm and Haas Company
InventorsH. Edwin Carley, Ashok K. Sharma
Life of this patent
Estimating the term…
Abstract
Certain N-acetonylbenzamides exhibit low toxicity to plants are particularly useful for control of fungi, especially Phycomycetes.
Claims19
A compound of the formula:
- ##STR10## wherein:
- A is a chloro, bromo, fluoro, iodo, trifluoromethyl, trifluoromethoxy, fluorosulfonyl, methyl, ethyl, phenyl, methoxy, chloromethyl, (C.sub.1 -C.sub.2) alkoxycarbonyl, cyano or hydroxy group;
- A.sup.1 and B are each independently selected from the group consisting of hydrogen, chloro, bromo, fluoro and methyl group;
- X is bromo, iodo, fluoro, cyano, thiocyano, isothiocyano, methylsulfonyloxy, thio(C.sub.1 -C.sub.2)alkyl, (C.sub.1 -C.sub.2)alkoxy, carbamoyloxy of the formula (--OC(O)N(R.sup.3).sub.2), thiocarbamoylthio of the formula (--SC(S)N(R.sup.3).sub.2), hydroxy, azide, (C.sub.1 -C.sub.4)alkylcarbonyloxy, phenylcarbonyloxy, phenoxy, phenylthio, trifluoromethylcarboxy, (C.sub.1 -C.sub.3)alkylthioacetyl, imidazolyl or triazolyl group;
- and when X is a phenylcarbonyloxy, phenoxy or phenylthio substituent, the phenyl moiety may be substituted with one substituent selected from the group consisting of chloro, fluoro, bromo, iodo or methyl group;
- Y and Z are each independently a hydrogen, bromo, chloro, iodo, fluoro, cyano, thiocyano, isothiocyano, methylsulfonyloxy, thio(C.sub.1 -C.sub.2)alkyl, (C.sub.1 -C.sub.2)alkoxy, carbamoyloxy of the formula (--OC(O)N(R.sup.3).sub.2), hydroxy, azide or (C.sub.1 -C.sub.4)alkylcarbonyloxy group and either, but not both, Y or Z may be an imidazolyl or triazolyl group;
- provided when X and Y are halogens and Z is hydrogen or X, Y and Z are all halogens, then the halogens are all the same halogen;
- further provided that when
- X is cyano, thiocyano, isothiocyano, methylsulfonyloxy, thio(C.sub.1 -C.sub.2)alkyl, (C.sub.1 -C.sub.2)alkoxy, carbamoyloxy of the formula (--OC(O)N(R.sup.3).sub.2), thiocarbamoylthio of the formula (--SC(S)N(R.sup.3).sub.2), azide, (C.sub.1 -C.sub.4)alkylcarbonyloxy, phenylcarbonyloxy, phenoxy, phenylthio, trifluoromethylcarboxy, imidazolyl or triazolyl group;
- and when X is a phenylcarbonyloxy, phenoxy or phenylthio substituent, the phenyl moiety may be substituted with one substituent selected from the group consisting of chloro, fluoro, bromo, iodo or methyl group;
- Y and Z are not a hydrogen, cyano, thiocyano, isothiocyano, methylsulfonyloxy, thio(C.sub.1 -C.sub.2)alkyl, (C.sub.1 -C.sub.2)alkoxy, carbamoyloxy of the formula (--OC(O)N(R.sup.3).sub.2), azide (C.sub.1 -C.sub.4)alkylcarbonyloxy, imidazolyl, or triazolyl group;
- R.sup.1 and R.sup.2 are each independently a hydrogen atom or a (C.sub.1 -C.sub.6)alkyl group;
- and each R.sup.3 is independently a hydrogen or a (C.sub.1 -C.sub.4)alkyl group.
10 more elements
The compound N-3'-(1',1'-dibromo-3'-methyl-2'-oxopentan)!-3,5-dichlorobenzamide.
Dependencies are inferred from the claim text.