Acylated nitrogen compounds useful as additives for lubricating oil and fuel compositions
AssigneeThe Lubrizol Corporation
InventorMark R. Baker
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Abstract
A process for reacting certain carboxylic reactants and at least one aldehyde or ketone with olefinic compounds then reacting the product prepared thereby with ammonia, a hydrazine or an amine, products prepared thereby and, additive concentrates, lubricating oil and fuel compositions.
Claims36
A lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of a composition prepared by a process comprising first reacting, optionally in the presence of an acidic catalyst selected from the group consisting of organic sulfonic acids, heteropolyacids, Lewis acids, and mineral acids,
- (A) at least one olefinic compound containing at least one group of the formula ##STR14## wherein the olefinic compound has the general formula (R.sup.1)(R.sup.2)C.dbd.C(R.sup.6)(CH(R.sup.7)(R.sup.8)) (III) wherein each R.sup.1 and R.sup.2 is, indepently, hydrogen or hydrocarbon based group, and each of R.sup.6, R.sup.7 and R.sup.8 is, indepently, hydrogen or hydrocarbon based group;
- and
- (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula
- R.sup.3 C(O)(R.sup.4).sub.n C(O)OR.sup.5 (IV)
- and compounds of the formula ##STR15## wherein each of R.sup.3, R.sup.5 and each R.sup.9 is independently H or a hydrocarbyl group, R.sup.4 is a divalent hydrocarbylene group, and n is 0 or 1, in amounts ranging from 0.6 moles (B) per mole of (A) to 1.5 moles (B) per equivalent of (A);
- and from about 0.5 to about 2 moles, per mole of (B), of
- (C) at least one aldehyde or ketone, then reacting the product formed thereby with from about 0.5 equivalents up to about 2 moles, per mole of (B) of at least one of
- (D) ammonia or a hydrazine or an amine characterized by the presence within its structure of at least one H--N group.
Dependencies are inferred from the claim text.