Environmentally improved acid corrosion inhibitor
AssigneeClearwater, Inc.
InventorsGary A. Scherubel, Robert Reid, Allen R. Fauke, Kevin Schwartz
Life of this patent
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Abstract
Corrosion is inhibited in hydrochloric acid solutions used to acidize wells, by adding to the solutions a corrosion inhibiting composition comprising cinnamaldehyde or a substituted cinnamaldehyde together with a reaction product of a C.sub.3-6 ketone such as acetophenone, thiourea or a related compound, formaldehyde and hydrochloric acid.
Claims13
Composition useful for inhibiting corrosion of ferrous metals by acidic solutions comprising, by weight, (a) about 10% to about 30% cinnamaldehyde or substituted cinnamaldehyde, (b) about 20% to about 50% ethylene glycol (c) about 5% to about 20% C.sub.8-12 ethoxylated alcohols, and (d) about 1% to about 15% of a composition comprising about 10% to about 40% isopropanol and a reaction product (based on the total composition in this section (d)) of
- about 10% to about 40% of a ketone having 3-9 carbon atoms,
- about 1% to about 10% urea, thiourea or an alkyl-substituted thiourea,
- about 25% to about 50% benzaldehyde or formaldehyde calculated as a 37% solution,
- about 1% to about 10% HCl, said reaction being conducted in the presence of about 5% to about 20% ethylene glycol by warming the reactants in a vessel equipped with a reflux condenser, at a temperature slightly below that at which formaldehyede or benzaldehyde would collect in the condenser, and then refluxing the reaction mixture for at least six hours.
Dependencies are inferred from the claim text.