Polyolefin fibers containing antimicrobial siloxane quaternary ammonium salts

A fiber having antimicrobial properties made from a melt-extrudable composition of which comprises:

• at least one thermoplastic polyolefin adapted to be shaped into a product by melt extrusion;
• and
• at least one additive which is adapted to surface segregate upon extrusion of said composition to impart antimicrobial properties to a surface of said product, wherein said additive has either the general formula A, ##STR19## wherein:
• (1) each of R.sub.1 -R.sub.7 is independently selected from the group consisting of monovalent C.sub.1 -C.sub.20 alkyl, phenyl, and phenyl-substituted C.sub.1 -C.sub.20 alkyl groups, in which each phenyl can be substituted or unsubstituted;
• (2) each of R.sub.8 and R.sub.9 is a monovalent group independently selected from the group consisting of (a) hydrogen and (b) monovalent alkyl, cycloalkyl, aryl, and heterocyclic groups and combinations thereof having up to about 30 carbon atoms, except that both R.sub.8 and R.sub.9 cannot be hydrogen;
• or, when taken together in combination with the carbon atom to which they are attached, R.sub.8 and R.sub.9 represent a carbonyl group;
• (3) each of R.sub.10 and R.sub.11 is a methyl group;
• (4) a represents an integer from 1 to about 20;
• (5) b represents an integer from 1 to about 20;
• (6) Z is a monovalent group having from about 8 to about 30 carbon atoms and selected from the group consisting of alkyl, cycloalkyl, aryl, and heterocyclic groups, and combinations thereof, wherein Z is terminated by an alkyl moiety which includes at least about 8 carbon atoms in a single continuous chain;
• (7) Y.sub.1 is an anion which does not cause the thermal instability of the additive to be more than about 35 weight percent decomposition during melt extrusion;
• and
• (8) said additive has a molecular weight of from about 600 to about 1,700;
• or the general formula B, ##STR20## wherein:
• (1) each of R.sub.20 -R.sub.23 is independently selected from the group consisting of monovalent C.sub.1 -C.sub.20 alkyl, phenyl, and phenyl-substituted C.sub.1 -C.sub.20 alkyl groups, in which each phenyl can be substituted or unsubstituted;
• (2) n represents an integer of from 1 to about 19;
• (3) each of Q.sub.1 and Q.sub.2 represents an independently selected quaternary ammonium group having the general formula, ##STR21## in which:
• (a) R.sub.24 is a monovalent alkyl group having from about 8 to about 30 carbon atoms, at least about 8 carbon atoms of which make up a single continuous chain:
• (b) R.sub.25 and R.sub.26 are methyl groups;
• (c) each of R.sub.27 and R.sub.28 is a monovalent group independently selected from the group consisting of (i) hydrogen and (ii) monovalent alkyl, cycloalkyl, aryl, and heterocyclic groups and combinations thereof having up to about 30 carbon atoms, except that both R.sub.27 and R.sub.28 cannot be hydrogen;
• or, when taken together in combination with the carbon atom to which they are attached, R.sub.27 and R.sub.28 represent a carbonyl group,
• (d) c represents an integer of from 2 to about 20;
• and
• (e) d represents an integer of from 2 to about 20;
• (4) Y.sub.2 represents an anion which does not cause the thermal instability of the additive to be more than about 35 weight percent decomposition during melt extrusion;
• and
• (5) said additive has a polydispersity of up to about 3.0 and a weight-average molecular weight of from about 800 to about 2,000;
• wherein said additive is present in said melt-extrudable composition in an amount sufficient to impart antimicrobial activity to the surfaces of a shaped article prepared therefrom by a melt-extrusion process.