Method of sizing paper using a sizing agent and a polymeric enhancer and paper produced thereof
AssigneeHercules Incorporated
InventorKyle J. Bottorff
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Abstract
Paper sizing enhancer that is a polymerization reaction product of a quaternary diallylammonium monomer and a diallylammonium monomer, as well as compositions containing the sizing enhancer and a sizing agent. The method of sizing paper with such paper sizing enhancer compound and a sizing agent provides sized paper with significantly improved sizing property characteristics, and the sized paper exhibits high print quality when used in inkjet printing applications.
Claims62
A method of producing sized paper with enhanced sizing property characteristics which comprises employing in the manufacture of sized paper sizing agent and a sizing enhancer that is a polymerization reaction product of monomer consisting essentially of at least one quaternary diallylammonium monomer of formula (I):
- ##STR7## and at least one diallylammonium monomer of formula (II):
- ##STR8## where R.sub.1A, R.sub.1B, R.sub.1C and R.sub.1D are independently hydrogen or C.sub.1 -C.sub.22 straight chain or branched alkyl;
- R.sub.2 and R.sub.3 are independently alkyl, alkenyl or aryl;
- R.sub.4 is hydrogen, alkyl, alkenyl or aryl;
- and
- X.sup.- is a monovalent anion or a multivalent equivalent of a monovalent anion, wherein the sizing enhancer contains about 20 to about 98 mole percent of units from the monomer of formula (I) and about 80 to about 2 mole percent of units from the monomer of formula (II) and wherein the sizing agent and size enhancer are added in amounts sufficient to produced a sized paper containing from about 0.005 wt % to about 1.5 wt % of the sizing agent, and from about 0.002 wt % to about 0.6 wt % of the sizing enhancer, based on the weight of the dried sized paper.
Sized paper prepared with sizing agent and a sizing enhancer that is a polymerization reaction product of monomers consisting essentially of at least one quaternary diallylammonium monomer of formula (I):
- ##STR9## and at least one diallylammonium monomer of formula (II):
- ##STR10## where R.sub.1A, R.sub.1B, R.sub.1C and R.sub.1D are independently hydrogen or C.sub.1 -C.sub.22 straight chain or branched alkyl;
- R.sub.2 and R.sub.3 are independently alkyl, alkenyl or aryl;
- R.sub.4 is hydrogen, alkyl, alkenyl or aryl;
- and
- X.sup.- is a monovalent anion or a multivalent equivalent of a monovalent anion,
- wherein the sizing enhancer contains about 20 to about 98 mole percent of units from the monomer of formula (I) and about 80 to about 2 mole percent of units from the monomer of formula (II) and wherein the amount of sizing agent and size enhancer in the sized paper is from about 0.005 wt % to about 1.5 wt %, and 0.002 wt % to about 0.6 wt % respectively, based on the weight of the dried sized paper.
The sized paper of 43 wherein the polymerization reaction product and the paper sizing agent are present in a weight ratio of from about 021:1 to about 3:1.
Dependencies are inferred from the claim text.