Base resistant fluorinated polymers
AssigneeE. I. Du Pont de Nemours and Company
InventorPaul Gregory Bekiarian
Life of this patent
Estimating the term…
Abstract
Disclosed herein are copolymers of tetrafluoroethylene and n-alkyl trifluorovinyl ether which further contain either curesite repeat units and/or iodine. Such curesite repeat units, upon exposure to free radicals, may crosslink the copolymers. The iodine is introduced by carrying out free radical polymerization in the presence of an organic iodide chain transfer agent. The polymers according to the invention are especially useful as elastomers and/or as molding resins for articles or parts that may be exposed to a basic environment. The preparation of such polymers by aqueous emulsion polymerization is also disclosed.
Claims16
A polymer comprising the following repeat units:
- ##STR3## and (III), a repeat unit that is crosslinkable by exposure to free radicals, wherein (III) is selected from the four member group (a)-(d) consisting of
- (a) a repeat unit having a pendant alkyl group having at least one methine hydrogen atom, ##STR4## wherein i and k is an integer in the range of 2 to 10, j is an integer in the range of 1 to 4, and each R.sup.2 is independently an alkyl group containing 1 to 4 carbon atoms;
- by means of which the polymer is readily crosslinked upon exposure of said polymer to free radicals;
- wherein R.sup.1 is an alkyl containing 1 to 6 carbon atoms;
- provided that (I)+(II)+(III) are at least about 50 mole percent of the repeat units in said polymer.
A free radical polymerization process for preparing a fluoropolymer, which is not crosslinked, which process comprises reacting an admixture of monomers comprising at least 50 mole percent of a combination of (1) tetrafluoroethylene, (2) at least one monomer within the formula CF.sub.2 .dbd.CFOR.sup.1, wherein R.sup.1 is an alkyl containing 1 to 6 carbon atoms, and (3) at least one crosslink-functional comonomer of which the corresponding repeat unit enables the product polymer to readily crosslink upon exposure of said fluoropolymer to free radicals;
- wherein the polymerization process is carried out in an aqueous emulsion at a temperature of from about 30.degree. to 80.degree. C. at a tetrafluoroethylene pressure of about 1 to 6 MPa.
Dependencies are inferred from the claim text.