Sulfur tolerant hydrocarbon conversion catalyst
AssigneeUop LLC
InventorsLeonid B. Galperin, Robert L. Bedard
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Abstract
Applicants have developed a catalyst for various hydrocarbon conversion processes which is tolerant to the presence of large amounts of sulfur (1000 ppm) in the feedstream. The catalyst consists of a molecular sieve support such as MeAPSO or zeolite Y that has dispersed thereon palladium and a modifier such as lanthanum.
Claims18
A process for preparing a catalytic composite consisting essentially of a molecular sieve support having dispersed thereon palladium and a modifier, and a binder, the support selected from the group consisting of Me.sub.x APSO, zeolite Y and mixtures thereof, where Me is a metal selected from the group consisting of magnesium, manganese, cobalt, iron, zinc, and mixtures thereof, x has a value from greater than zero to about 0.5, the modifier selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, samarium, gadolinium, terbium, and mixtures thereof and the binder is selected from the group consisting of alumina, silica, silica/alumina, and mixtures thereof, the process comprising impregnating the support with an aqueous solution containing a palladium compound and a modifier compound, drying the impregnated support at a temperature of about 600.degree. C. to about 300.degree. C. to give a dried catalytic composite and treating the dried catalytic composite at a temperature of about 300.degree. C. to about 500.degree. C. with a H.sub.2 /H.sub.2 S gas mixture for a time of about 1 to about 10 hours thereby providing said composite.
Dependencies are inferred from the claim text.