An optical waveguide assembly which comprises a substrate, and at least one waveguide on the substrate, each said waveguide comprising a substantially transparent, shaped polymeric core having a plurality of edges, which core is attached on and raised from a surface of the substrate on one edge of the core, and a shaped, polymeric, light reflecting cladding attached on and in substantially conforming registration with each other edge of the core such that the cladding has a shape substantially congruent with the shape of the core and wherein the refractive index of the cladding is less than the refractive index of the core.