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AssigneeBASF SE
InventorsThomas Greindl, Alfred Oftring, Gerold Braun, Jochen Wild, Birgit Potthoff-Karl, Georg Schuh
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Glycine-N,N-diacetic acid derivatives I ##STR1## where R is unsubstituted or substituted alkyl, alkenyl, alkoxylate groups, phenylalkyl, phenyl, a heterocyclic ring or a radical of the formula ##STR2## where A is an alkylene bridge or a chemical bond, and M is hydrogen, alkali metal, alkaline earth metal, ammonium or substituted ammonium in the appropriate stoichiometric amounts, are prepared by reacting A) corresponding 2-substituted glycines or 2-substituted glycinonitriles or doubled glycines of the formula ##STR3## or doubled glycinonitriles of the formula ##STR4## or precursors of the glycine derivatives named as starting material with formaldehyde and hydrogen cyanide in aqueous medium at a pH of from 0 to 11 or B) iminodiacetonitrile or iminodiacetic acid with appropriate monoaldehydes of the formula R--CHO or dialdehydes of the formula OHC--A--CHO and hydrogen cyanide in aqueous medium at a pH of from 0 to 11 and, where appropriate, subsequent hydrolysis of nitrile functionalities which are present, where the starting material used comprises unpurified raw material derived from the industrial synthesis of glycine derivatives or their precursors or of iminodiacetonitrile or iminodiacetic acid, or mother liquors produced in such syntheses.
A process for preparing a glycine-N,N-diacetic acid derivative of the formula I ##STR10## where R is C.sub.1 -C.sub.30 -alkyl or C.sub.2 -C.sub.30 -alkenyl, each of which can additionally carry as substituents up to 5 hydroxyl groups, formyl groups, C.sub.1 -C.sub.4 -alkoxy groups, phenoxy groups or C.sub.1 -C.sub.4 -alkoxycarbonyl groups and can be interrupted by up to 5 nonadjacent oxygen atoms, or alkoxylate groups of the formula --(CH.sub.2).sub.k --O--(A.sup.1 O).sub.m --(A.sup.2 O).sub.n --Y, where A.sup.1 and A.sup.2 are, independently of one another, 1,2-alkylene groups having 2 to 4 carbon atoms, Y is hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl or C.sub.1 -C.sub.4 -alkoxycarbonyl, and k is 1, 2 or 3 and m and n are each from 0 to 50, it being necessary for the total of m+n to be at least 4, phenylalkyl groups having 1 to 20 carbon atoms in the alkyl, phenyl, a five- or six-membered unsaturated or saturated heterocyclic ring which has up to three hetero atoms from the group consisting of nitrogen, oxygen and sulfur and which can additionally be benzo-fused, or a radical of the formula ##STR11## where A is a C.sub.1 -C.sub.12 -alkylene bridge or a chemical bond, and M is hydrogen, alkali metal, alkaline earth metal, ammonium or substituted ammonium in the appropriate stoichiometric amounts, comprising reacting an unpurified raw material of:
Dependencies are inferred from the claim text.