Blocked polyisocyanate composition and one-pack thermocuring resin composition comprising the same
AssigneeAsahi Kasei Kogyo Kabushiki Kaisha
InventorsTaketoshi Usui, Yoshiyuki Asahina
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AssigneeAsahi Kasei Kogyo Kabushiki Kaisha
InventorsTaketoshi Usui, Yoshiyuki Asahina
Estimating the term…
Disclosed is a blocked polyisocyanate composition comprising: a blocked polyisocyanate obtained by blocking the terminal isocyanate groups of a two or more terminal isocyanate groups-containing polyisocyanate derived from at least one diisocyanate selected from an aliphatic diisocyanate and an alicyclic diisocyanate with a blocking agent comprising at least one active methylene compound selected from a malonic diester and an acetoacetic ester; and a salt of a basic compound with an acidic compound, or a mixture of the salt with the basic compound or the acidic compound, the composition having a pH value of from 1 to 8.5. The blocked polyisocyanate composition of the present invention not only exhibits high stability even under high temperature conditions, but also is capable of maintaining such high stability for a prolonged period of time. The blocked polyisocyanate composition can be combined with a polyol to provide a one-pack thermocuring resin composition which exhibits not only excellent storage stability but also excellent curability even under low temperature conditions, which therefore can be advantageously used as various coating materials, adhesives, sealing agents and the like.
A blocked polyisocyanate composition comprising:
A method for producing a blocked polyisocyanate composition, comprising reacting a two or more terminal isocyanate groups-containing polyisocyanate derived from at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with a blocking agent comprising at least one active methylene compound selected from the group consisting of a malonic diester and an acetoacetic acid ester in the presence of a basic compound to obtain a reaction mixture containing the basic compound, and reacting said reaction mixture with an acidic compound in an amount sufficient to neutralize the basic compound and cause the resultant blocked polyisocyanate composition to have a pH value of from 2 to 6.5.
Dependencies are inferred from the claim text.