A process for the preparation of an isomeric mixture of .alpha.-anomeric isomer and .beta.-anomeric isomer of a glycoside compound possessing surface activity wherein the weight ratio of the .alpha.-isomer to the .beta.-isomer is within the range of 80/20-5/95, said process comprising:
- reacting a saccharide compound of the following general formula:
- Z(OH).sub.q
- wherein Z is a saccharide skeleton and q is the number of hydroxyl groups connected to the saccharide skeleton, in the presence of a solid acid catalyst with a glycerol derivative of the following general formula:
- HO (C.sub.3 H.sub.5 (OH)O).sub.x --R
- wherein 1<x.ltoreq.7 and wherein R is an aliphatic group having 1-12 carbon atoms when x=1 and 13-22 carbon atoms when x is 2-7.