US 5,849,408 AGranted

Hot-dip zinc plating product

AssigneeNippon Mining & Metals Co., Ltd.

InventorNoriaki Sugawara

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Abstract

When a hot-dip zinc plating layer, which contains Al, is applied on rimmed steel having an Si level of less than 0.05% by weight or less, by the two-stage plating method, appearance failure can be prevented by setting the plating conditions as follows: in a first zinc bath consisting of zinc of 99.7% purity or more or in a second zinc bath which consists of zinc with 99.7% purity by weight or more and 0.05% or less of Al at a temperature of from more than 460.degree. C. to 490.degree. C. and for a dipping time of from 1 minute to 1.5 minutes; and, in a second zinc bath consisting of zinc of 99.7% purity by weight and from 2 to 10% by weight or less of Al at a temperature of from 400.degree. C. to less than 430.degree. C. and for a dipping time of from 0.5 minute to 1.5 minutes. This plating condition provides a plating structure that the Zn, Fe and Al are present in the essentially entire portion of the plating layer. The Zn-centration increases in the direction from the boundary to the top of said layer; the Al concentration decreases in the direction from the boundary to the top of said layer.

Claims3

Dependent claims

A hot-dip zinc plated steel, comprising:

a rimmed steel having an Si content of less than 0.05% by weight, a C content of 0.3% by weight or less and a Mn content of 0.50% by weight or less;
and,
a hot-dip zinc plating layer formed on a surface of the steel and consisting of from 5 to 30% by weight of Al, not more than 20% by weight of Fe, the balance being Zn and unavoidable impurities, and in which Zn, Al and Fe are present essentially in the entire thickness of the layer, the Zn content is lowest near the surface of the steel and is highest at the surface of the layer and the Al content is highest near the surface of the steel and lowest at the surface of the layer;
said hot-dip zinc plated steel being formed by a successive two-stage hot-dip galvanizing, wherein:
in a first stage hot-dip zinc plating step, a plating bath consists of zinc of 99.7% purity by weight or more and 0.05% by weight or less of Al, and has a temperature of from about 463.degree. C. to about 481.degree. C. and wherein a dipping time of the steel in the plating bath is from 1 minute to 1.5 minutes;
and,
in a second stage hot-dip zinc plating step, a plating bath consists of zinc of 99.7% purity by weight or more and from 2 to 10% by weight of Al, and has a temperature of from about 422.degree. C. to about 425.degree. C., and wherein a dipping time of the steel in the plating bath is from 0.5 minute to 1.5 minutes.

4 more elements

Dependencies are inferred from the claim text.

Facts

Application: 08/665,348Filed 17 Jun 1996 · continuation in part
Priority: JP 5-34689327 Dec 1993
Granted: 15 Dec 1998
Term ends: Not estimatedThe source records don’t support an estimate.

Classification7 codes

C23C 2/024
Pretreatment of the material to be coated, e.g. for coating on selected surface areas: by cleaning or etching
Y10T 428/12736
Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]: al-base component
Y10T 428/12799
Zn-base component: next to Fe-base component [e.g., galvanized]
Y10T 428/12951
Group VIII or IB metal-base component: fe-base component