Method for decolorization of alkanolamines and alkyleneamines
AssigneeUnion Carbide Chemicals & Plastics Technology Corporation
InventorCharles Arnold Gibson
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Abstract
Color-containing alkanolamines or alkyleneamines, having color numbers of up to 100 PtCo or higher, can be treated with polymeric solid acidic catalysts at elevated temperatures. Perfluorinated ion-exchange polymers in the acid form may be used as the polymeric solid acidic catalyst. In the presence of added water, these polymeric solid acidic catalysts produce decolorized alkanolamines or alkyleneamines having color numbers of 20 PtCo or less. The process of decolorization can be carried out in batch or continuous mode processes thus providing low cost, high quality and high purity end products.
Claims6
A method of producing alkanolamines or alkyleneamines having a reduced color comprising contacting, in the presence of about 1 to about 10% by weight of the material to be decolorized of added water, maintained in the liquid phase at a temperature of 201.degree. to about 230.degree. C. and a pressure of about 1 to about 100 psig, color-containing alkanolamines or alkyleneamines with a polymeric solid acidic catalyst to reduce the color of said alkanolamines or alkyleneamines.
Dependencies are inferred from the claim text.