Molecular organic compound with ferromagnetic properties and a method of producing it

A method of producing an organic compound with ferromagnetic properties, comprising a molecular compound with one of the following general formulae :

• L--A--Z (I)
• L--A'--L' (II)
• where:
• --A-- is selected from a radical from a benzene nucleus which is multivalent in the para position and which is optionally substituted, and a radical from a naphthalene nucleus which is multivalent in the position para to one of the nuclei and which is optionally substituted;
• --Z-- is a mono- or bivalent radical selected from hydrogen, a nitrile radical, a nitro radical, a fluoro radical, a chloro radical, a bromo radical, an iodo radical, an amino radical, an imino radical, an alkylamino radical, a dialkylamino radical, a dialkylimino radical, a trialkylammonio radical, an aminocyclic radical in which one carbon atom in the ring is optionally substituted by a heteroatom, a sulfo radical, a carboxy radical, a phosphono radical, an arsono radical, an acyl radical, a formamido radical, an acetamido radical and an acetimido radical;
• --A'-- is selected from a radical from a benzene nucleus which is multivalent in the para or ortho position and which is optionally substituted;
• --L and --L' have the form:
• ##STR16## where N is a nitrogen atom;
• where:
• --X is a mono- or bivalent radical which can fix a proton, selected from a first group consisting of an amino radical, an imino radical, an alkylamino radical, a dialkylamino radical, a dialkylimino radical, a trialkylammonio radical and an aminocyclic radical in which one carbon atom in the ring is optionally substituted by a heteroatom, or selected from a second group consisting of a sulfo radical, a carboxy radical, a phosphono radical and an arsono radical;
• --NR-- and --NR'-- are multivalent radicals from a primary amine or ammonia where N is a nitrogen atom;
• --B-- is selected from a radical from a naphthalene nucleus in which one of the nuclei is bonded to nitrogen atoms positioned para to each other and in which the other nucleus has at least one substituent Y in the 6 or 7 position, a radical from a multivalent benzene nucleus which has at least one substituent Y in the 2 or 3 position bonded to the nucleus via an ethenylene link or a paraphenylene link which is optionally substituted, said substituent Y being selected from a sulfo radical, a carboxy radical, a phosphono radical, and an arsono radical when --X is selected from the first group of compounds, and said substituent Y being selected from an amino radical, an imino radical, an alkylamino radical, a dialkylamino radical, a dialkylimino radical, a trialkylammonio radical and an aminocyclic radical in which one carbon atom in the ring is optionally substituted by a heteroatom when --X is selected from said second group of compounds,
• said organic compound being in its reduced form or in its oxidized form,
• said method comprising forming a chain of at least one aminoaromatic compound, which is optionally substituted, with an aminosulfonic acid containing two condensed benzene nuclei, said chain being formed in an alcoholic solution, in the presence of a weak acid and an oxidizing agent.