Process for growing a film epitaxially upon a MGO surface and structures formed with the process
AssigneeLockheed Martin Energy Systems, Inc.
InventorsRodney Allen McKee, Frederick Joseph Walker
Life of this patent
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Abstract
A process and structure wherein optical quality perovskites, such as BaTiO.sub.3 or SrTiO.sub.3, are grown upon a single crystal MgO substrate involves the epitaxial build up of alternating planes of TiO.sub.2 and metal oxide wherein the first plane grown upon the MgO substrate is a plane of TiO.sub.2. The layering sequence involved in the film build up reduces problems which would otherwise result from the interfacial electrostatics at the first atomic layers, and these oxides can be stabilized as commensurate thin films at a unit cell thickness or grown with high crystal quality to thicknesses of 0.5-0.7 .mu.m for optical device applications.
Claims6
A structure comprising:
- a (001) oriented MgO substrate;
- and
- a (100) oriented epitaxial plane consisting of TiO.sub.2 grown cube-on-cube on the MgO substrate wherein the plane consisting of TiO.sub.2 directly contacts the MgO substrate and is commensurate with the MgO substrate.
A structure comprising:
- a (001) oriented MgO substrate;
- a first plane consisting of (100) oriented TiO.sub.2 grown cube-on-cube on the MgO substrate, wherein the plane consisting of TiO.sub.2 directly contacts the MgO substrate and is commensurate with the MgO surface;
- and
- a second plane consisting of a (100) oriented metal oxide grown cube-on-cube on the first plane consisting of TiO.sub.2 wherein the second plane consisting of a metal oxide directly contacts and is commensurate with the TiO.sub.2 plane and said metal oxide is selected from the group consisting of BaO, SrO, CaO and MgO.
A structure for use in a semiconductor or wave guide application comprising:
- a (001) oriented MgO substrate;
- and
- an epitaxial plane consisting of a (100) oriented TiO.sub.2 grown cube-on-cube on the MgO substrate, wherein the plane consisting of TiO.sub.2 directly contacts the MgO substrate and is commensurate with the MgO substrate.
Dependencies are inferred from the claim text.