Pressure swing adsorption process and apparatus
AssigneeThe BOC Group, Inc.
InventorShain-Jer Doong
Life of this patent
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Abstract
A process and apparatus for separating the components of a gas mixture in a pair of adsorption vessels using a single gas compressor/pump to move gas into and out of the adsorption vessels. The cycle is such that the gas compressor/pump is in continuous operation. The adsorption cycle is non-symmetrical in that the series of steps carried out in one of the adsorbers is not the same as the series of steps carried out in the other adsorber. The apparatus includes an intermediate gas storage container which is used to temporarily store gas removed from the nonadsorbed gas outlet end of the adsorption vessels so that it can be used to partially pressurize the adsorption vessels upon completion of the adsorbent regeneration step of the adsorption cycle.
Claims29
A process for producing first component-enriched gas from a feed gas containing first and second components in a system comprising at least one gas reservoir and at least two adsorption zones each containing an adsorbent which selectively adsorbs said second component, comprising repeatedly performing the steps:
- (i) producing first component-enriched gas in one of said adsorption zones by cocurrently introducing feed gas thereinto and cocurrently removing first component-enriched gas therefrom, while partially depressurizing another of said adsorption zones by cocurrently transferring gas therefrom and into said gas reservoir;
- (ii) partially depressurizing one of said adsorption zones by cocurrently transferring gas therefrom and into said gas reservoir, while countercurrently removing second component-enriched gas from another of said adsorption zones;
- (iii) purging one of said adsorption zones by transferring gas cocurrently out of another adsorption zone and countercurrently into said one of said adsorption zones of this step (iii) while countercurrently withdrawing gas therefrom;
- (iv) countercurrently removing second component-enriched gas from one of said adsorption zones, while partially pressurizing another of said adsorption zones by countercurrently transferring gas thereinto from said gas reservoir;
- (v) purging one of said adsorption zones other than the adsorption zone purged in step (iii) by countercurrently transferring gas thereinto from said gas reservoir and countercurrently removing second component-enriched gas from said one of said adsorption zones of this step (v), while further pressurizing the adsorption zone partially pressurized in step (iv) by cocurrently introducing feed gas thereinto;
- (vi) partially pressurizing one of said adsorption zones by countercurrently transferring gas thereinto from said gas reservoir, while producing first component-enriched gas by cocurrently introducing feed gas into another of said adsorption zones other than said one adsorption zone of step (i) and cocurrently removing first component-enriched gas therefrom;
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- (vii) further pressurizing the adsorption zone partially pressurized in step (vi) by cocurrently introducing feed gas thereinto, while continuing to cocurrently introduce feed gas into said another of said adsorption zones referred to in step (vi) and cocurrently removing first component-enriched gas therefrom.
A process for producing first component-enriched gas from a feed gas containing first and second components in a system comprising at least one gas reservoir and one or more pairs of first and second adsorption zones, each adsorption zone containing an adsorbent which selectively adsorbs said second component, comprising, with respect to each pair of first and second adsorption zones, repeatedly performing the steps:
- (i) producing first component-enriched product gas by cocurrently introducing feed gas into said first adsorption zone and cocurrently removing first component-enriched gas therefrom, while partially depressurizing said second adsorption zone by cocurrently transferring gas therefrom and into said gas reservoir;
- (ii) partially depressurizing said first adsorption zone by cocurrently transferring gas therefrom and into said gas reservoir, while countercurrently removing second component-enriched gas from said second adsorption zone;
- (iii) purging said second adsorption zone by transferring gas cocurrently out of said first adsorption zone and countercurrently into said second adsorption zone while countercurrently removing second component-enriched gas from said second adsorption zone;
- (iv) countercurrently removing second component-enriched gas from said first adsorption zone, while partially pressurizing said second adsorption zone by countercurrently transferring gas thereinto from said gas reservoir;
- (v) purging said first adsorption zone by countercurrently transferring gas thereinto from said gas reservoir and countercurrently removing gas from said first adsorption zone;
- while further pressurizing said second adsorption zone by cocurrently introducing feed gas thereinto;
- (vi) partially pressurizing said first adsorption zone by countercurrently transferring gas thereinto from said gas reservoir, while producing first component-enriched product gas by cocurrently introducing feed gas into said second adsorption zone and cocurrently removing first component-enriched gas therefrom;
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- (vii) further pressurizing said first adsorption zone by cocurrently introducing feed gas thereinto, while continuing to produce first component-enriched product gas by cocurrently introducing feed gas into said second adsorption zone and cocurrently removing first component-enriched gas therefrom.
A system for fractionating a feed gas comprising:
- (a) first and second adsorption zones each having an inlet and outlet and each containing an adsorbent which selectively adsorbs one component of said feed gas;
- (b) a gas storage container having an opening;
- (c) gas pumping means having an inlet and an outlet;
- (d) adsorption zone exhaust gas conduit means connecting the inlet of each adsorption zone to said gas pumping means inlet, said adsorption zone exhaust gas conduit means including valve means to cut off communication between either or both of said adsorption zone inlets and said gas pumping means inlet;
- (e) first feed gas conduit means with valve means connecting a feed gas source and said gas pumping means inlet;
- (f) second feed gas conduit means with valve means connecting said feed gas source and said adsorption zone inlets;
- (g) adsorption zone feed conduit means connecting the outlet of said gas pumping means to the inlet of each adsorption zone, said adsorption zone feed conduit means including valve means to cut off communication between said gas pumping means outlet and either or both of said adsorption zone inlets;
- (h) exhaust gas discharge conduit means with valve means connecting said gas pumping means outlet to an exhaust gas discharge point;
- (i) product gas conduit means connecting the outlet of each adsorption zone to a product gas discharge point, said product gas conduit means including valve means to cut off communication between either or both of said adsorption zone outlets and said product gas discharge point;
- (j) cross-connection conduit means with valve means connecting the outlets of said adsorption zones;
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- (k) intermediate storage conduit means connecting the outlets of each adsorption zone to said opening of said gas storage container, said intermediate gas storage means conduit means including valve means to cut off communication between either or both of said adsorption zone outlets and said opening of said gas storage container.
Dependencies are inferred from the claim text.