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US 5,811,383 AGranted
High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
AssigneeThe Dow Chemical Company
InventorsJohn Klier, Christopher J. Tucker, Gary M. Strandburg
Life of this patent
Estimating the term…
Abstract
Superior high water containing oil continuous microemulsions and emulsions for cleaning contain defined amounts of water, one or more ionic surfactants, and one or more organic solvents so that the compositions have a low conductivity and low viscosity.
Claims16
An emulsion, which upon standing at 25.degree. C. forms at least two phases wherein one phase is an oil continuous microemulsion, comprising:
- A) water in an amount greater than 60 percent by weight and less than 95 percent by weight based on the total weight of the emulsion;
- B) an organic solvent or a mixture of two or more organic solvents, wherein the organic solvent or mixture of organic solvents are characterized as containing no more than 2 weight percent water at 25.degree. C. when the organic solvent is saturated with water in the absence of surfactants or other additives, and wherein the organic solvent or the mixture of two or more organic solvents are in an amount greater than 4 percent and less than 40 percent by weight based on the total weight of the emulsion;
- C) one or more ionic surfactants which are soluble in the one or more organic solvents, wherein the one or more ionic surfactants have a molecular weight in the range from 350 to 700, and wherein the one or more ionic surfactants are present in a total amount greater than 0.1 percent and less than 5 percent by weight based on the total weight of the emulsion;
- the emulsion characterized as being an oil continuous emulsion, wherein the emulsion has an electrical conductivity of less than 10,000Z microSiemens/centimeter when measured at use temperatures and a viscosity less than 40 centistokes as measured at use temperatures, wherein Z is represented by the following formula:
- Z=(1/30,000) (.phi..sub.w).sup.2 .SIGMA..sub.i A.sub.i m.sub.i, wherein .phi..sub.w represents the volume fraction of water in the microemulsion, i represents any electrolyte which is present in the microemulsion, A.sub.i represents the molar conductivity of electrolyte i and m.sub.i represents the molarity of electrolyte in the aqueous phase.
2 more elements
A cleaning concentrate which comprises:
- Component A) an organic solvent or a mixture of two or more organic solvents, wherein the organic solvent or mixture of organic solvents are characterized as containing no more than 1 weight percent water at 25.degree. C. when the organic solvent is saturated with water in the absence of surfactants or other additives;
- and
- Component B) one or more ionic surfactants which are soluble in Component A), wherein the one or more ionic surfactants have a molecular weight in the range from 350 to 700, exclusive of a counterion;
- which cleaning concentrate is capable of dilution with water to form a microemulsion which is characterized as being oil continuous, said microemulsion comprising:
- (i) water present in an amount greater than 45 percent and less than 70 percent, by weight, based on the total weight of the microemulsion;
- (ii) Component A) present in an amount greater than 15 percent and less than 50 percent, by weight, based on the total weight of the microemulsion;
- and
- (iii) Component B) present in an amount greater than 0.1 percent and less than 6 percent, by weight, based on the total weight of the microemulsion.
5 more elements
Dependencies are inferred from the claim text.