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US 5,804,101 AGranted
Nonlinear optical materials with reduced aromaticity and bond length alternation
AssigneeCalifornia Institute of Technology
InventorsSeth R. Marder, Lap-Tak Cheng
Life of this patent
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Abstract
Compositions for use in non-linear optical devices. The compositions have high first molecular electronic hyperpolarizability (.beta.) and therefore display high second order non-linear optical properties when incorporated into non-linear optical devices. The acceptor and donor groups which are used in the compositions, along with the .pi.(pi)-bridge length is chosen to optimize second-order non-linear optical responses.
Claims4
A nonlinear electro-optical device comprising:
- A) an element comprising a composition of matter which exhibits a second-order nonlinear optical response, said composition having the formula:
- ##STR21## wherein A is ##STR22## R is H, alkyl or aryl;
- wherein B is ##STR23## D is OR", NR"R'" or SR";
- where R" is aryl;
- R'" is aryl;
- or where NR" or R'" are derived from a cyclic amine of the form N(CH.sub.2).sub.l where l=3-10, and
- wherein m is 2 or 3;
- and
- where the asterisk indicates the point of attachment on the acceptor and donor;
- and
- B) means for directing at least one incident beam of electromagnetic radiation having at least one frequency into said element whereby electromagnetic radiation emerging from said element has at least one frequency which is different from said at least one frequency of said incident beam of electromagnetic radiation.
8 more elements
Dependencies are inferred from the claim text.