Method for producing elemental sulfur from sulfur-containing gases
AssigneeResearch Triangle Institute
InventorsThomas P. Dorchak, Santosh K. Gangwal, Scott M. Harkins
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Abstract
A method for producing elemental sulfur and reduced/oxidized sulfur compounds from sulfur containing gases. The method comprises mixing a primary gas stream of sulfur-containing gases with a secondary gas stream to produce a combined gas stream having a preselected stoichiometry and contacting the combined gas stream with a catalyst at a pressure of 7 to 100 atmospheres and a temperature of 540.degree. to 700.degree. C. The catalyst is selected from the group consisting of silica, titania, alumina, sodium/alumina, zinc titanate, alumina or titania promoted with transition metals nickel, cobalt, molybdenum, tungsten, alloys and mixtures thereof and mixture of such catalysts.
Claims5
A method for producing elemental sulfur and sulfur compounds from sulfur containing gases, comprising mixing a primary gas stream consisting essentially of sulfur dioxide with a secondary reducing gas stream comprising at least one of hydrogen or carbon monoxide to prepare a gaseous mixture feed material, contacting a catalyst selected from the group consisting of silica, alumina, sodium impregnated alumina, zinc titanate, titania and transition metals selected from the group consisting of nickel, cobalt, tungsten, molybdenum, mixtures and alloys of these transition metals supported on alumina or titania with said feed material, at a pressure of 7-100 atmospheres and a temperature of 54.degree. C.-700.degree. C., and recovering 52.3-99.7% of the sulfur containing gases of said primary gas stream as elemental sulfur and reduced sulfur compounds from the product of said catalyst/feed material contacting step.
Dependencies are inferred from the claim text.