Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
AssigneeHoechst Celanese Corporation
InventorsJerry D. Unruh, Brigitte E. Segmuller, Gabriel R. Chapa, Kent E. Pryor
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Abstract
Hydroformylation of alkenes to aldehydes in the presence of a rhodium complex catalyst is improved by the addition of a novel bidentate ligand of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.1 ' and R.sub.2 ' are organic radicals selected from alicyclic, aliphatic and aromatic groups of which at least one is preferably substituted with at least one electronegative moiety and the methylene groups are present at the trans-2,3 positions on the norbomane moiety. The invention also provides a novel method for producing the bidentate ligand and novel intermediate phosphine oxide and phosphinous acid compounds.
Claims2
A method of hydroformulating an ethylenically unsaturated compound having from 2-25 carbon atoms with hydrogen and carbon monoxide in a liquid phase reaction zone to produce an aldehyde derivative of said ethylenically unsaturated compound, comprising hydroformulating said compound in the presence of rhodium in complex combination with 1,2-bisbis(3,5-difluorophenyl)phosphino!-5-fluorobenzene.
A method of hydroformulating ethylenically unsaturated compound having from 2-25 carbon atoms with hydrogen and carbon monoxide in a liquid phase reaction zone to produce an aldehyde derivative of said ethylenically unsaturated compound, comprising hydroformulating said compound in the presence of rhodium in complex combination with 1,3-bisbis(3,5-difluorophenyl)-phosphino!-5-fluorobenzene.
Dependencies are inferred from the claim text.