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US 5,786,459 AGranted
Tetrazo dyestuffs
AssigneeBayer Aktiengesellschaft
InventorsFrank-Michael Stohr, Peter Wild
Life of this patent
Estimating the term…
Abstract
Compounds of the formula (I) ##STR1## have been found which are suitable for dyeing and printing hydroxyl- and/or amido-containing substrates, in particular for printing paper by the ink-jet method.
Claims12
A compound of the formula (I) ##STR63## in which T represents the radical of a tetrazo component,
- R.sup.1 denotes hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,
- R.sup.2 and R.sup.3 together with the N atom to which they are bonded form a saturated or unsaturated 3- to 8-membered ring containing no further heteroatoms or containing 1 or 2 further heteroatoms selected from the group consisting of O, S, SO, SO.sub.2 and NR, where R is H or substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -hydroxyalkyl or C.sub.1 -C.sub.4 -aminoalkyl,
- X represents NR.sup.2 R.sup.3
- ring A is unsubstituted or further substituted with one or more members of the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, OH, S--C.sub.1 -C.sub.4 -alkyl, NR.sup.4 R.sup.5 wherein R.sup.4 and R.sup.5, independently of one another represent hydrogen, or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by one or more water solubilizing groups selected from the group consisting of SO.sub.3 H, OSO.sub.3 H, and COOH;
- SO.sub.3 H, COOH, --NR.sup.1 COC.sub.1 -C.sub.4 -alkyl, NR.sup.1 COC.sub.6 -C.sub.10 -aryl, --NR.sup.1 --SO.sub.2 --C.sub.1 -C.sub.4 -alkyl, NR.sub.1 --SO.sub.2 --C.sub.6 -C.sub.10 -aryl, --NR.sup.1 CONH.sub.2, --NR.sup.1 --COCH.sub.2 OH, NR.sup.1 COOC.sub.1 -C.sub.4 -alkyl and NR.sup.2 R.sup.3 wherein the substituents for the substituted alkyl radicals in the definitions of R.sup.1, R.sup.1' and R are selected from the group consisting of OH, C.sub.1 -C.sub.4 -alkoxy, Cl, F, Br, COOH, SO.sub.3 H, OSO.sub.3 H, NR.sup.4 R.sup.5, R.sup.4 and R.sup.5 having the meanings given above, and combinations thereof,
- K denotes a radical of the formula (II) ##STR64## in which m represents 1,
- R.sup.1' denotes hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,
- R.sup.2' and R.sup.3' together with the N atom to which they are bonded form a saturated or unsaturated 3- to 8-membered ring containing no further heteroatoms or containing 1 or 2 further heteroatoms selected from the group consisting of O, S, SO, SO.sub.2 and NR, where R is H or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -hydroxyalkyl or C.sub.1 -C.sub.4 -aminoalkyl,
- X' represents NR.sup.2' R.sup.3'
- ring A' is not further substituted or is further substituted with one or more members of the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, OH, S--C.sub.1 -C.sub.4 -alkyl, NR.sup.4 R.sup.5 wherein R.sup.4 and R.sup.5, independently of one another represent hydrogen, or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by one or more water solubilizing groups selected from the group consisting of SO.sub.3 H, OSO.sub.3 H, and COOH;
- SO.sub.3 H, COOH, --NR.sup.1 COC.sub.1 -C.sub.4 -alkyl, NR.sup.1 COC.sub.6 -C.sub.10 -aryl, --NR.sup.1 --SO.sub.2 --C.sub.1 -C.sub.4 -alkyl, NR.sub.1 --SO.sub.2 --C.sub.6 -C.sub.10 -aryl, --NR.sup.1 CONH.sub.2, --NR.sup.1 --COCH.sub.2 OH, NR.sup.1 COOC.sub.1 -C.sub.4 -alkyl and NR.sup.2 R.sup.3
- wherein the substituents for the substituted alkyl radicals in the definitions of R.sup.1, R.sup.1' and R are selected from the group consisting of OH, C.sub.1 -C.sub.4 -alkoxy, Cl, F, Br, COOH, SO.sub.3 H, OSO.sub.3 H, NR.sup.4 R.sup.5, R.sup.4 and R.sup.5 having the meanings given above, and combinations thereof.
9 more elements
An aqueous dyestuff preparation containing
- 0.5 to 20% by weight of one or more dyestuffs, at least one of which is a compound according to claim 1,
- 50 to 99.5% by weight of water,
- 0 to 30% by weight of one or more organic solvents,
- 0 to 30% by weight of additives affecting the viscosity and/or surface tension, the sum of the ingredients mentioned adding up to 100% by weight.
1 more element
Dependencies are inferred from the claim text.