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US 5,770,729 AGranted
Ozonide reducing agent
AssigneeOtsuka Kagaku Kabushiki Kaisha
InventorsMichio Sasaoka, Daisuke Suzuki, Takashi Shiroi
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Abstract
The present invention provides an ozonide reducing agent for use in the ozonolysis reaction of an organic compound, the ozonide reducing agent finding wide applications, and being safe and inexpensive from a commercial viewpoint and easy to treat for disposal. The ozonide reducing agent of the invention is a compound wherein sulfur has, at both ends of its molecule, a hydrocarbon residue substituted by a polar functional group.
Claims3
A method of reducing an ozonide, comprising:
- adding an ozonide reducing agent to an ozonide-containing solvent in an amount sufficient to reductively decompose the ozonide, said ozonide reducing agent being one or more compounds selected from the group consisting of a compound represented by the formula
- X--R.sup.1 --R.sup.2 --S--R.sup.3 --R.sup.4 --Y (1)
- wherein R.sup.1 and R.sup.4 are the same or different and each represents a single bond or a straight- or branched-chain C.sub.1-6 alkylene group;
- R.sup.2 and R.sup.3 are the same or different and each is a straight- or branched-chain C.sub.1-6 alkylene group, a straight- or branched-chain C.sub.2-8 alkenylene group, a straight- or branched-chain C.sub.2-6 alkynylene group, a C.sub.3-8 cycloaklylene group or a phenylene group which may have a C.sub.1-6 alkyl group and/or an amino group as a substituent on the phenyl ring;
- X and Y are the same or different and each represents a hydroxyl group, a nitrile group or a carboxyl group;
- and a compound represented by the formula
- R.sup.5 --S--R.sup.6 ( 2)
- wherein R.sup.5 and R.sup.6 are the same or different and each represents thienyl, furyl, pyridyl, pyranyl, pyrrolyl, chromenyl, imidazolyl, pyrazolyl, thiazolyl, oxazolyl, pyrazinol, pyrimidyl, pyridazinyl, or quinolyl, having as a substituent at least one group selected from a hydroxyl group, a hydroxymethyl group, a nitrile group, a cyanomethyl group, a carboxyl group and a carboxymethyl group;
- reductively decomposing the ozonide with said ozonide reducing agent;
- and
- removing the sulfoxide resulting from the ozonolysis reaction of said ozonide with said ozonide reducing agent.
8 more elements
Dependencies are inferred from the claim text.