Activated zeolite beta and its use for hydrocarbon conversion
AssigneeUop LLC
InventorsGary W. Skeels, Edith M. Flanigen
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AssigneeUop LLC
InventorsGary W. Skeels, Edith M. Flanigen
Estimating the term…
The present invention relates to a zeolite beta catalyst characterized by critical limits of weak and strong acid species and exceptionally high catalytic activity. The catalyst is activated at a temperature effective to substantially reduce the concentration of strong acid species, i.e., hydronium cations, without substantially reducing the concentration of weak acid species, i.e., hydroxoaluminum cations, preferably following a calcining step wherein a synthesized zeolite beta catalyst containing a templating agent is calcined at a temperature in the range of from about 200.degree. to 1000.degree. C. in order to remove a substantial portion of the catalyst templating agent and an ion-exchanging step wherein the calcined catalyst is ion-exchanged with a salt solution containing at least one hydrogen forming cation selected from NH.sub.4.sup.+ and quaternary ammonium. Conversion processes utilizing the catalyst of the invention, including isomerization of paraffins and alkylaromatics and disproportionation of aromatics, also are disclosed.
A process for the disproportionation of an alkylaromatic feedstock comprising one or both of toluene and trimethylbenzenes comprising contacting the feedstock at alkylaromatic-disproportionation conditions with an activated zeolite beta catalyst having a concentration of hydroxoaluminum cations corresponding to at least 0.9 milliequivalents of NaOH per gram of zeolite beta and a concentration of hydronium cations corresponding to less than 0.1 milliequivalents of NaOH per gram of zeolite beta to obtain an disproportionated alkylaromatic product containing a greater proportion of xylenes than in the feedstock.
Dependencies are inferred from the claim text.