Process for hydrotreating metal-contaminated hydrocarbonaceous feedstock
AssigneeShell Oil Company
InventorsAndries Qirin Maria Boon, Constantinus Johannes Jacobus Den Ouden, Opinder Kishen Bhan
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AssigneeShell Oil Company
InventorsAndries Qirin Maria Boon, Constantinus Johannes Jacobus Den Ouden, Opinder Kishen Bhan
Estimating the term…
The present invention provides a process for hydrotreating a metal-contaminated hydrocarbonaceous feedstock of which at least 60% wt. boils at a temperature 370.degree. C., the process comprising contacting the feedstock at elevated temperature and elevated pressure in the presence of hydrogen with one or more catalyst beds each of a first catalyst, a second catalyst and a third catalyst, wherein (i) the first catalyst comprises a Group VI and/or a Group VIII hydrogenation metal component on an inorganic oxide support having at least 40% of its pore volume in pores with diameters in the range from 17 nm to 25 nm and a surface area in the range from 100 m.sup.2 /g to 160 m.sup.2 /g; (ii) the second catalyst comprises a Group VI and/or a Group VIII hydrogenation metal component on an inorganic oxide support having at least 40% of its pore volume in pores with diameters in the range from 3 nm to 17 nm and a surface area in the range from 160 m.sup.2 /g to 350 m.sup.2 /g; and (iii) the third catalyst comprises a Group VI and a Group VIII hydrogenation metal component on an inorganic oxide support having at least 40% of its pore volume in pores with diameters in the range from 17 nm to 25 nm and a surface area in the range from 100 m.sup.2 /g to 160 m.sup.2 /g; the third catalyst being at least 1.5 times more active for demetallization than the first catalyst at contaminant metal deposition levels less than 5% wt.
A process for hydrotreating a metal-contaminated hydrocarbonaceous feedstock of which at least about 60% wt. boils at a temperature.gtoreq.370.degree. C., which comprises contacting the feedstock at elevated temperature and elevated pressure in the presence of hydrogen with one or more catalyst beds each of a first catalyst, a second catalyst and a third catalyst where first, second and third designate the order of the catalyst contact with said feed, wherein
A process for converting a hydrocarbonaceous feedstock into lower boiling materials, which comprises contacting a metal-contaminated hydrocarbonaceous feedstock of which at least about 60% wt. boils at a temperature.gtoreq.370.degree. C., at elevated temperature and elevated pressure in the presence of hydrogen with one or more catalyst beds each of a first catalyst, a second catalyst and a third-catalyst, where first, second and third designate the order of the catalyst contact with said feed, wherein
Dependencies are inferred from the claim text.